利用有害甲烷生产有价值的甲醇:催化方面的进展

Sayanti Datta, Dipravath Kumar Seth
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引用次数: 0

摘要

作为一种温室气体,甲烷对生物多样性构成威胁。因此,通过将甲烷转化为甲醇等有价值的化学物质来加以利用是最有前途的再行动之一。为了解决这个问题,人们对甲烷转化为甲醇(MTM 工艺)进行了大量研究。然而,迄今为止,在工业规模上用甲烷生产甲醇仍是一项重大挑战。经过深入研究,本综述文章仅简要讨论了那些已报道的方法,这些方法利用天然、异质、非热等离子体、固定在固体床中的纳米颗粒等多种不同的熔融体生产出令人满意的甲醇。为了深入研究,我们分析了各类催化剂在大规模生产甲醇过程中效率低下的原因,并对不同催化剂的活性进行了比较。在此,还重点介绍了在常温常压下效率相对较高的催化剂。为了大规模生产甲醇,本研究还提出了未来规划战略的一些基本概念,以便设计出更合适的反应系统。
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Production of Valuable Methanol from Hazardous Methane: Advances in the Catalysis
Being a greenhouse gas, methane is a threat to biodiversity. Hence, the utilization of methane by converting it into a valuable chemical like methanol is one of the most promising re-actions. To solve that problem, a large number of studies have been performed on methane-to-methanol conversion (MTM process). Still, to date, the production of methanol from methane on an industry scale is a crucial challenge. After a thorough study, in this review article, only those reported methods, which produce a satisfactory yield of methanol using a large variety of cata-lysts like natural, heterogeneous, non-thermal plasma, nanoparticles fixed in solid bed, etc., have been briefly discussed. To investigate minutely, the reason behind the inefficiency of each type of catalyst in producing methanol on a large scale has been analyzed, and a comparison among the activities of different catalysts has been made. Herein, catalysts with comparatively better ef-ficiency under ambient temperature and pressure have also been highlighted. With the hope of producing methanol on a large scale, some basic concepts of future planning strategies for de-signing more suitable reaction systems are also proposed in this study
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