S. Mondal, S. K. Chaudhuri, J. K. Saha, P. K. Mukherjee, B. Fricke
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引用次数: 0
摘要
以共轭位置空间和动量空间中的香农熵和费雪熵为基础的量子信息理论度量提供了关于任意约束环境下原子间电荷密度的局域化/去局域化模式的重要信息。在这篇文章中,我们尝试将这种测量方法应用于嵌入H等电子离子(核电荷,Z=2-5)的弱耦合经典等离子体的基态、激发态和双光子跃迁产生的虚态(\(1s\rightarrow nl\);\(n=2-4\), \(l=0,2\))。上述状态的波函数本质上是斯莱特型轨道的线性组合,其系数由变分框架内的四阶时变扰动理论产生。在共轭空间中,香农和费雪测量值与等离子体筛选参数图具有互补性。针对自由离子和等离子体束缚离子的虚态和实态 2p 态,提出了一种新的缩放定律来复制香农熵和费雪熵随 Z 的变化。
Quantum information-theoretical analysis on the two-photon transitions in hydrogen isoelectronic ions under plasma confinement
Quantum information-theoretical measure in terms of Shannon and Fisher entropy in conjugate position and momentum spaces provides important information about the localization/delocalization patterns of the inter-atomic charge density under arbitrary confining environments. In this article, we have attempted to employ such measures to the ground, excited, and the virtual states arising out of two-photon transitions (\(1s\rightarrow nl\); \(n=2-4\), \(l=0,2\)) of weakly coupled classical plasma embedded H iso-electronic ions (nuclear charge, \(Z = 2 - 5\)). The wavefunction for the said states is essentially a linear combination of the Slater-type orbitals, the coefficients of which are generated from a fourth-order time-dependent perturbation theory within the variational framework. A complementary nature has been noted in the Shannon and Fisher measures versus the plasma screening parameter plot in the conjugate spaces. A novel scaling law has been proposed to replicate the variation of the Shannon and Fisher entropy w.r.t.Z for the virtual as well as real 2p states of free and plasma confined ions.
期刊介绍:
The European Physical Journal D (EPJ D) presents new and original research results in:
Atomic Physics;
Molecular Physics and Chemical Physics;
Atomic and Molecular Collisions;
Clusters and Nanostructures;
Plasma Physics;
Laser Cooling and Quantum Gas;
Nonlinear Dynamics;
Optical Physics;
Quantum Optics and Quantum Information;
Ultraintense and Ultrashort Laser Fields.
The range of topics covered in these areas is extensive, from Molecular Interaction and Reactivity to Spectroscopy and Thermodynamics of Clusters, from Atomic Optics to Bose-Einstein Condensation to Femtochemistry.