{"title":"利用 SbCl5 氧化剂通过 OCVD 方法制造高共形 PEDOT 涂层,从而提高碳布电极的电容量","authors":"Meysam Heydari Gharahcheshmeh, Kafil Chowdhury","doi":"10.1002/admi.202400118","DOIUrl":null,"url":null,"abstract":"<p>Carbon cloth shows potential for flexible energy storage electrodes but encounters challenges such as low specific capacitance and limited wettability. This study addresses these limitations by fabricating a highly conformal coating of poly(3,4-ethylenedioxythiophene) (PEDOT) around 3D carbon fibers via the oxidative chemical vapor deposition (oCVD) method, employing antimony pentachloride (SbCl<sub>5</sub>) as the oxidant. The oCVD stands out as a robust manufacturing technique for fabricating highly conformal conducting polymer films on porous structures, ensuring the preservation of geometric features and the maintenance of active sites for redox reactions. The resulting PEDOT-coated carbon cloth electrodes exhibit improved pseudocapacitance and specific capacitance compared to their pristine counterparts. Particularly, oCVD PEDOT-coated carbon cloth fabricated at various deposition temperatures exhibit a substantial 1.5- to 2.3-fold enhancement in specific capacitance compared to pristine carbon cloth. The highest specific capacitance (170.94 F g⁻¹) is attained in the oCVD PEDOT-coated carbon cloth fabricated at a deposition temperature of 80 °C, representing a 2.3-fold enhancement over its pristine counterpart. The PEDOT-coated carbon cloths demonstrate lower charge transfer resistance compared to their pristine counterparts, further confirming their superior electrochemical performance. This investigation highlights oCVD's effectiveness in fabricating highly conformal PEDOT coating on carbon cloth electrodes for electrochemical energy storage devices.</p>","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400118","citationCount":"0","resultStr":"{\"title\":\"Enhancing Capacitance of Carbon Cloth Electrodes via Highly Conformal PEDOT Coating Fabricated by the OCVD Method Utilizing SbCl5 Oxidant\",\"authors\":\"Meysam Heydari Gharahcheshmeh, Kafil Chowdhury\",\"doi\":\"10.1002/admi.202400118\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Carbon cloth shows potential for flexible energy storage electrodes but encounters challenges such as low specific capacitance and limited wettability. This study addresses these limitations by fabricating a highly conformal coating of poly(3,4-ethylenedioxythiophene) (PEDOT) around 3D carbon fibers via the oxidative chemical vapor deposition (oCVD) method, employing antimony pentachloride (SbCl<sub>5</sub>) as the oxidant. The oCVD stands out as a robust manufacturing technique for fabricating highly conformal conducting polymer films on porous structures, ensuring the preservation of geometric features and the maintenance of active sites for redox reactions. The resulting PEDOT-coated carbon cloth electrodes exhibit improved pseudocapacitance and specific capacitance compared to their pristine counterparts. Particularly, oCVD PEDOT-coated carbon cloth fabricated at various deposition temperatures exhibit a substantial 1.5- to 2.3-fold enhancement in specific capacitance compared to pristine carbon cloth. The highest specific capacitance (170.94 F g⁻¹) is attained in the oCVD PEDOT-coated carbon cloth fabricated at a deposition temperature of 80 °C, representing a 2.3-fold enhancement over its pristine counterpart. The PEDOT-coated carbon cloths demonstrate lower charge transfer resistance compared to their pristine counterparts, further confirming their superior electrochemical performance. This investigation highlights oCVD's effectiveness in fabricating highly conformal PEDOT coating on carbon cloth electrodes for electrochemical energy storage devices.</p>\",\"PeriodicalId\":115,\"journal\":{\"name\":\"Advanced Materials Interfaces\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-05-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202400118\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/admi.202400118\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials Interfaces","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/admi.202400118","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Enhancing Capacitance of Carbon Cloth Electrodes via Highly Conformal PEDOT Coating Fabricated by the OCVD Method Utilizing SbCl5 Oxidant
Carbon cloth shows potential for flexible energy storage electrodes but encounters challenges such as low specific capacitance and limited wettability. This study addresses these limitations by fabricating a highly conformal coating of poly(3,4-ethylenedioxythiophene) (PEDOT) around 3D carbon fibers via the oxidative chemical vapor deposition (oCVD) method, employing antimony pentachloride (SbCl5) as the oxidant. The oCVD stands out as a robust manufacturing technique for fabricating highly conformal conducting polymer films on porous structures, ensuring the preservation of geometric features and the maintenance of active sites for redox reactions. The resulting PEDOT-coated carbon cloth electrodes exhibit improved pseudocapacitance and specific capacitance compared to their pristine counterparts. Particularly, oCVD PEDOT-coated carbon cloth fabricated at various deposition temperatures exhibit a substantial 1.5- to 2.3-fold enhancement in specific capacitance compared to pristine carbon cloth. The highest specific capacitance (170.94 F g⁻¹) is attained in the oCVD PEDOT-coated carbon cloth fabricated at a deposition temperature of 80 °C, representing a 2.3-fold enhancement over its pristine counterpart. The PEDOT-coated carbon cloths demonstrate lower charge transfer resistance compared to their pristine counterparts, further confirming their superior electrochemical performance. This investigation highlights oCVD's effectiveness in fabricating highly conformal PEDOT coating on carbon cloth electrodes for electrochemical energy storage devices.
期刊介绍:
Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018.
The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface.
Advanced Materials Interfaces covers all topics in interface-related research:
Oil / water separation,
Applications of nanostructured materials,
2D materials and heterostructures,
Surfaces and interfaces in organic electronic devices,
Catalysis and membranes,
Self-assembly and nanopatterned surfaces,
Composite and coating materials,
Biointerfaces for technical and medical applications.
Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.