使用 (2-2-(4-Dinitrophenyl) Hydrazono) 甲基苯酚在电位传感器中测定铁的实验方法

IF 0.9 4区 材料科学 Science of Advanced Materials Pub Date : 2024-06-01 DOI:10.1166/sam.2024.4657
M. M. Abdullah, Hasan B. Albargi, JariS. Algethami, Shashank Sharma, Mohammad Luqman, Jawed Mustafa
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引用次数: 0

摘要

研究介绍了一种基于聚氯乙烯膜的铁(III)电位传感器,该传感器在铁(III)离子选择性电极(ISE)中表现出令人印象深刻的选择性。该传感器的检测限为 4.0×10-7 M,在 7.4×10-7 至 1×10-1 M 的浓度范围内,每十进制变化的 Nernstian 响应斜率为 19.4 mV。该传感器可在 3.6-10 的 pH 值范围内有效工作,至少可在八周内保持其潜在的无发散效用,并具有约 20 秒的快速响应时间。传感器对 Fe3+ 离子的选择性使其成为特异性检测 Fe(III)离子的有力工具。传感器的可靠性和使用寿命使其成为连续监测应用的重要工具,可在各种环境中及时提供有关铁离子存在情况的准确信息。
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Experimental Approaches to Iron Determination in Potentiometric Sensors Using (2-2-(4-Dinitrophenyl) Hydrazono) Methylphenol
The study presents a PVC membrane-based potentiometric sensor for iron (III) detection, demonstrating impressive selectivity in Fe(III) ion-selective electrodes (ISE). The sensor achieves a detection limit of 4.0×10−7 M and a Nernstian response slope of 19.4 mV per decade change within a concentration range of 7.4×10−7 to 1×10−1 M. Operating efficiently within the pH range of 3.6–10, the sensor maintains its potential divergence-free utility for at least eight weeks and has a rapid response time of approximately twenty seconds. The sensor’s selectivity for Fe3+ ions makes it a robust tool for specific Fe(III) ion detection. The sensor’s reliability and longevity make it a valuable tool for continuous monitoring applications, providing accurate and timely information on the presence of iron ions in diverse settings.
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来源期刊
Science of Advanced Materials
Science of Advanced Materials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
自引率
11.10%
发文量
98
审稿时长
4.4 months
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