通过异质成核和溶质驱动的生长限制协同策略增强镁-Zr 母合金对镁合金的晶粒细化效果

IF 2.9 2区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Acta Metallurgica Sinica-English Letters Pub Date : 2024-06-06 DOI:10.1007/s40195-024-01719-8
Gang Zeng, Hong Liu, Jing-Peng Xiong, Jian-Long Li, Yong Liu
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引用次数: 0

摘要

锆(Zr)是镁(Mg)合金中最有效的晶粒细化剂。通常,锆以 Mg-Zr 母合金的形式引入。然而,在 Mg-Zr 母合金中,Zr 主要以颗粒形式存在,由于具有吸引力的范德华力,往往会聚集在一起。聚集的 Zr 容易沉降,从而降低其对镁合金的精炼影响。在这项工作中,提出了一种镁-锆母合金的组合预处理工艺,包括引入物理场干预颗粒锆的聚集,以及采用高温溶解和包晶反应促进锆的固溶。结果表明,预处理后的 Mg-Zr 母合金中的颗粒 Zr 得到了有效的分散和细化,并能获得更高的溶质 Zr 含量。随后对典型的 Mg-6Zn-0.6Zr (wt%) 合金的晶粒细化能力进行了研究。结果表明,在 60 分钟的保温时间内,Mg-Zr 母合金的晶粒细化效率提高了 32.4%。经过预处理的 Mg-Zr 母合金通过异质成核和溶质驱动生长限制的协同策略,显著提高了镁合金的晶粒细化效率。在镁合金中实现有效的 Zr 晶粒细化的关键因素在于调节 Mg-Zr 母合金中 Zr 的存在和形态,区分颗粒 Zr 和溶质 Zr。本研究介绍了一种开发更高效 Mg-Zr 精炼剂的新方法。
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Enhanced Grain Refining Effect of Mg–Zr Master Alloy on Magnesium Alloys via a Synergistic Strategy Involving Heterogeneous Nucleation and Solute-Driven Growth Restriction

Zirconium (Zr) emerges as the most effective grain refiner for magnesium (Mg) alloys incorporating Zr. Typically, Zr is introduced in the form of an Mg–Zr master alloy. However, within Mg–Zr master alloys, Zr predominantly exists in a particle form, which tends to aggregate due to attractive van der Waals forces. The clustered Zr is prone to settling, thereby reducing its refining impact on Mg alloys. In this work, a combined pretreatment process for Mg–Zr master alloys was proposed, encompassing the introduction of a physical field to intervene the agglomeration of particle Zr and the employ of high-temperature dissolution and peritectic reactions to promote the solid solution of Zr. The results demonstrate that the particle Zr within the pretreated Mg–Zr master alloy is effectively dispersed and refined, and greater solute Zr levels can be achieved. The subsequent grain refinement ability was studied on a typical Mg–6Zn–0.6Zr (wt%) alloy. The outcome highlights that an improvement in the grain refinement efficacy (32.4%) of Mg–Zr master alloys was obtained with a holding time of 60 min. The pretreated Mg–Zr master alloy significantly augments the efficiency of grain refinement for Mg alloys through a synergistic strategy involving heterogeneous nucleation and solute-driven growth restriction. The crucial factor in achieving effective grain refinement of Zr in Mg alloys lies in regulating the presence and morphology of Zr in the Mg–Zr master alloy, distinguishing between particle Zr and solute Zr. This study introduces a novel method for developing more efficient Mg–Zr refiners.

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来源期刊
Acta Metallurgica Sinica-English Letters
Acta Metallurgica Sinica-English Letters METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
6.60
自引率
14.30%
发文量
122
审稿时长
2 months
期刊介绍: This international journal presents compact reports of significant, original and timely research reflecting progress in metallurgy, materials science and engineering, including materials physics, physical metallurgy, and process metallurgy.
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