革新能源和环境应用的生态友好型催化剂:概述

IF 2.8 3区 化学 Q2 CHEMISTRY, APPLIED Topics in Catalysis Pub Date : 2024-06-21 DOI:10.1007/s11244-024-01976-y
Ali Hussain, Imania Ghaffar, Sanaullah Sattar, Muhammad Muneeb, Ali Hasan, Balakrishnan Deepanraj
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引用次数: 0

摘要

催化剂对于在不改变反应本身的情况下加速化学反应至关重要。催化剂可以是均相催化剂,也可以是异相催化剂,其中异相催化剂由于能耗低、成本效益高而更受认可。酶等生物催化剂具有高度选择性和高效性。催化剂的性能受理想孔隙率、孔宽、表面积以及稀土金属、碱金属和碱土金属等促进剂等因素的影响。多价金属作为均相或异相催化剂的有效性取决于多种变量,包括共存、pH 值、配方等。目前,磁铁矿、橄榄石和钛铁矿等铁基催化剂因其成本低、反应活性高和稳定性强而备受关注。金属有机框架因其孔隙率高、比表面积大以及能够改变孔隙的大小和形状,作为催化剂载体而备受关注。全球人口的不断增长导致了环境污染和能源危机,因此需要清洁的可再生能源。本综述重点介绍纳米催化剂和生物炭催化剂等可持续绿色催化剂在高效、可持续生产生物燃料方面的潜力和作用。此外,本综述还讨论了金属氧化物、杂多酸和铝硅酸盐催化剂在废水修复中的应用。
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Eco-friendly Catalysts Revolutionizing Energy and Environmental Applications: An Overview

Catalysts are essential for accelerating chemical reactions without altering the reaction itself. They can be homogeneous or heterogeneous, with heterogeneous catalysts being more recognized due to their lower energy consumption and cost-effectiveness. Biocatalysts, such as enzymes, are highly selective and efficient. The performance of catalysts is influenced by factors such as ideal porosity, pore width, surface area, and promoters like rare earth metals, alkaline, and alkaline earth metals. The effectiveness of multivalent metals as homogeneous or heterogeneous catalysts depends on a variety of variables, including coexistence, pH, formulation, and others. Currently, Fe-based catalysts, such as magnetite, olivine, and ilmenite, have gained interest due to their lower cost, higher reactivity, and stability. Metal-organic frameworks have gained interest as catalyst supports due to their high porosity, higher surface area, and ability to alter the size and shape of pores. The growing global population has led to environmental pollution and energy crises, necessitating the need for clean, renewable energy sources. This review focuses on the potential and utility of sustainable green catalysts like nanocatalysts and biochar-based catalysts for the efficient and sustainable production of biofuels. In addition, the usage of metal oxides, heteropoly acids, and aluminuminosilicate catalysts for wastewater remediation is also discussed in this review.

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来源期刊
Topics in Catalysis
Topics in Catalysis 化学-物理化学
CiteScore
5.70
自引率
5.60%
发文量
197
审稿时长
2 months
期刊介绍: Topics in Catalysis publishes topical collections in all fields of catalysis which are composed only of invited articles from leading authors. The journal documents today’s emerging and critical trends in all branches of catalysis. Each themed issue is organized by renowned Guest Editors in collaboration with the Editors-in-Chief. Proposals for new topics are welcome and should be submitted directly to the Editors-in-Chief. The publication of individual uninvited original research articles can be sent to our sister journal Catalysis Letters. This journal aims for rapid publication of high-impact original research articles in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis.
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