{"title":"硼烷基促进 C（sp2）-C（sp3）交叉偶联反应","authors":"Jesus Rodrigalvarez, Ruben Martin","doi":"10.1038/s44160-024-00586-6","DOIUrl":null,"url":null,"abstract":"Amine–borane adducts activate alkyl halides via halogen-atom transfer through boryl radical intermediates, enabling the formation of C(sp2)–C(sp3) bonds using either organometallic reagents or organic halides.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Boryl radicals facilitate C(sp2)–C(sp3) cross-coupling reactions\",\"authors\":\"Jesus Rodrigalvarez, Ruben Martin\",\"doi\":\"10.1038/s44160-024-00586-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Amine–borane adducts activate alkyl halides via halogen-atom transfer through boryl radical intermediates, enabling the formation of C(sp2)–C(sp3) bonds using either organometallic reagents or organic halides.\",\"PeriodicalId\":74251,\"journal\":{\"name\":\"Nature synthesis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nature synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1038/s44160-024-00586-6\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"N/A\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1038/s44160-024-00586-6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"N/A","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Amine–borane adducts activate alkyl halides via halogen-atom transfer through boryl radical intermediates, enabling the formation of C(sp2)–C(sp3) bonds using either organometallic reagents or organic halides.
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