具有优异电磁波吸收特性的形态可控 In2O3 纳米材料

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-06-25 DOI:10.1021/acsaelm.4c00830
Bonan Liu, Chuchu Yan, Qianqian Ren, Wei Li, Weihang Ma, Zhihao Liu, Han Zhang, Hongyang Zhu, Zhiyong Zhang, Wu Zhao, Yingnan Wang
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引用次数: 0

摘要

在电磁波吸收领域,开发吸收性能强、填充率低、带宽宽的非磁性材料具有重要意义。本研究通过简单的水热法和退火法制备了五种形态的 In2O3 纳米材料。通过使用不同的表面活性剂,获得了不同形态的产品(包括片状花朵形、荔枝形、奶酪形、纳米立方体和海胆状 In2O3)。实验结果表明,片花状 In2O3 的最小反射损耗(RLmin)为 -52.04 dB(1.74 mm),有效吸收带宽(EAB)为 5.97 GHz(1.92 mm)。相应地,荔枝状 In2O3 的 RLmin 和 EAB 分别为 -70.61 dB(2.55 mm)和 5.57 GHz(1.72 mm)。片花状 In2O3 的大比表面积可有效增加电磁波在吸收材料内部的反射和散射路径,有利于电磁波的衰减。这项工作不仅证明了 In2O3 在实际电磁波吸收应用中的巨大潜力,而且拓展了电磁波吸收领域对非磁性材料的研究。
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Morphology-Controlled In2O3 Nanomaterials with Excellent Electromagnetic Wave Absorption Properties
In the field of electromagnetic wave (EMW) absorption, the development of nonmagnetic materials with strong absorptive performance, low filling ratio, and wide bandwidth is of significant importance. In this work, five morphologies of In2O3 nanomaterials are prepared by simple hydrothermal and annealing processes. The morphologies of products (including the lamellar flower-, lychee-, cheese-, nanocube-, and urchin-like In2O3) are obtained by using different surfactants. The experimental results indicate that the lamellar flower-like In2O3 has a minimum reflection loss (RLmin) of −52.04 dB (1.74 mm) and an effective absorption bandwidth (EAB) of 5.97 GHz (1.92 mm). Correspondingly, the RLmin and EAB of lychee-like In2O3 are −70.61 dB (2.55 mm) and 5.57 GHz (1.72 mm), respectively. A large specific surface area about lamellar flower-like In2O3 can effectively increase the reflection and scattering paths of EMW inside the absorbing material, which is beneficial for the attenuation of EMW. This work not only demonstrates the great potential of In2O3 in practical EMW absorption applications but also extends the research on nonmagnetic materials in the EMW absorption field.
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