部分水解聚酰胺对油藏岩石的影响分析

Mihaela Helstern, Doru Stoianovici, T. Chiş
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摘要

由于对新油气田投资的增加,特别是由于环境立法方面的限制,重油油田的开采最近获得了迅猛发展。因此,我在这篇文章中介绍了在重质原油矿藏开采中使用部分水解聚丙烯酰胺的可能性,方法是将聚丙烯酰胺注入储层岩石,然后注入储层水。这种聚合物的作用是为原油和水的流动通道提供润滑,特别是(通过反渗透)阻塞大孔隙沟通通道,以限制不可控区域的压力泄漏。在这项研究中,我们创造了两种聚合物,用于提高流速、降低粘度和凝固点(添加剂很容易获得,尤其是在处理蒸馏器时效果显著,并且不会影响炼油厂最终产品的稳定性和质量)。我们还研究了聚合物在碳酸盐储层岩石中的流动,并设法获得了一个数值模型,该模型提供了岩石对部分流态化聚丙烯酰胺流动的阻力系数数据。岩石表面的吸附作用不仅降低了聚合物的流动性,还通过聚合物(聚合物链)的改性(交叉)改变了凝胶结构,从而导致堵塞(阻塞孔隙),增加了流体流动的可能性。在实验室中,我们测定了部分水解浓度为 0.05% 的聚丙烯酰胺水溶液对硅的吸附力,当氯化钠的浓度从 0 .我们还发现,对于渗透性为 140 mD 的多孔砂介质,用 20 g/l NaCl 取代盐水后,流出物中的聚合物浓度为 400 ppm,在注入 5 个孔隙后,这一数值基本稳定。
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Analysis of the Effects of Partially Hydrolyzed Polyamide on Oil Reservoir Rocks
The exploitation of heavy oil fields has recently gained momentum due to increased investment in new oil and gas fields and especially due to environmental legislative constraints. That is why in this article I have described the possibility of using partially hydrolyzed polyacrylamide in the exploitation of heavy crude oil deposits, by injecting it into reservoir rocks followed by injection of reservoir water. The role of this polymer is to provide lubrication of the crude oil and water flow channels and especially to block (by reverse osmosis) the large pore communication channels in order to limit pressure leaks in uncontrollable areas. In the study we created two polymers that were used in order to increase the flow rate and decrease the viscosity and the freezing point (additives that are easy to procure and especially with spectacular results in the treatment of stills and without affecting the stability and quality of the final products refinery). We also studied the flow of the polymer through carbonate reservoir rocks, managing to obtain a numerical model that provides data on the rock resistance factor to the flow of partially fluidized polyacrylamide. The adsorption on the surface of the rocks determined the reduction of the mobility of the polymer but also the modification of the gel structure by the modification (crossing) of the polymer (of the polymer chains) which led to clogging (blocking of the pores) and increasing the possibility of fluid flow. In the laboratory we determined the adsorption of silicon for a solution of polyacrylamide of 0.05% partially hydrolyzed concentration in water, it increases from the value of 0.01 mg/m2 to 0.05 mg/m2 when the concentration in NaCl increases from 0 .5% to 10% in are we showed that adsorption increases for pH values ​​lower than 7, and it is stated that for a porous sand medium with a permeability of 140 mD, replacing saline water with 20 g/l NaCl, a presence of the polymer with a concentration of 400 ppm was observed in the effluent, and this value being approximately stabilized after 5 injected pore volumes.
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