{"title":"通过同轴湿法纺丝生产的芯鞘 PVDF 中空多孔纤维用于能量收集","authors":"","doi":"10.1016/j.coco.2024.102019","DOIUrl":null,"url":null,"abstract":"<div><p>Flexible piezoelectric nanogenerators (PENGs), as a promising sustainable power source in smart electronics, have attracted much attention for their potential applications in the Internet of Things. In this paper, poly(vinylidene fluoride) (PVDF) fibers with core-sheath hollow porous structure were prepared by coaxial wet spinning process, serving as the dielectric layer, which were perfused internally by liquid metal (LM) as the inner electrode layer and wrapped outside by copper-silver nanoparticles (Cu@AgNP) as the outer electrode layer, thus constructing high-performance PVDF/LM/Cu@AgNP composite fibers. The composite PVDF fibers have a layered pore structure and arbitrarily deformable LM electrodes, which can significantly reduce the effective electric constant and thus enhance the piezoelectric properties. The results reveal that PVDF/LM/Cu@AgNP-PENG yields an optimal voltage output of 410 mV, providing a clear advantage over PENG by using alternative fibers. Moreover, the PVDF/LM/Cu@AgNP-PENG shows an excellent charging capability for energy storage devices, being able to charge 1 μF capacitors to 10 V within 30 s and directly power commercial LEDs. This study demonstrates the significant potential for utilizing composite PVDF piezoelectric fibers in flexible wearable electronic devices.</p></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":null,"pages":null},"PeriodicalIF":6.5000,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Core-sheath PVDF hollow porous fibers via coaxial wet spinning for energy harvesting\",\"authors\":\"\",\"doi\":\"10.1016/j.coco.2024.102019\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Flexible piezoelectric nanogenerators (PENGs), as a promising sustainable power source in smart electronics, have attracted much attention for their potential applications in the Internet of Things. In this paper, poly(vinylidene fluoride) (PVDF) fibers with core-sheath hollow porous structure were prepared by coaxial wet spinning process, serving as the dielectric layer, which were perfused internally by liquid metal (LM) as the inner electrode layer and wrapped outside by copper-silver nanoparticles (Cu@AgNP) as the outer electrode layer, thus constructing high-performance PVDF/LM/Cu@AgNP composite fibers. The composite PVDF fibers have a layered pore structure and arbitrarily deformable LM electrodes, which can significantly reduce the effective electric constant and thus enhance the piezoelectric properties. The results reveal that PVDF/LM/Cu@AgNP-PENG yields an optimal voltage output of 410 mV, providing a clear advantage over PENG by using alternative fibers. Moreover, the PVDF/LM/Cu@AgNP-PENG shows an excellent charging capability for energy storage devices, being able to charge 1 μF capacitors to 10 V within 30 s and directly power commercial LEDs. This study demonstrates the significant potential for utilizing composite PVDF piezoelectric fibers in flexible wearable electronic devices.</p></div>\",\"PeriodicalId\":10533,\"journal\":{\"name\":\"Composites Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Communications\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2452213924002109\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Communications","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2452213924002109","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Core-sheath PVDF hollow porous fibers via coaxial wet spinning for energy harvesting
Flexible piezoelectric nanogenerators (PENGs), as a promising sustainable power source in smart electronics, have attracted much attention for their potential applications in the Internet of Things. In this paper, poly(vinylidene fluoride) (PVDF) fibers with core-sheath hollow porous structure were prepared by coaxial wet spinning process, serving as the dielectric layer, which were perfused internally by liquid metal (LM) as the inner electrode layer and wrapped outside by copper-silver nanoparticles (Cu@AgNP) as the outer electrode layer, thus constructing high-performance PVDF/LM/Cu@AgNP composite fibers. The composite PVDF fibers have a layered pore structure and arbitrarily deformable LM electrodes, which can significantly reduce the effective electric constant and thus enhance the piezoelectric properties. The results reveal that PVDF/LM/Cu@AgNP-PENG yields an optimal voltage output of 410 mV, providing a clear advantage over PENG by using alternative fibers. Moreover, the PVDF/LM/Cu@AgNP-PENG shows an excellent charging capability for energy storage devices, being able to charge 1 μF capacitors to 10 V within 30 s and directly power commercial LEDs. This study demonstrates the significant potential for utilizing composite PVDF piezoelectric fibers in flexible wearable electronic devices.
期刊介绍:
Composites Communications (Compos. Commun.) is a peer-reviewed journal publishing short communications and letters on the latest advances in composites science and technology. With a rapid review and publication process, its goal is to disseminate new knowledge promptly within the composites community. The journal welcomes manuscripts presenting creative concepts and new findings in design, state-of-the-art approaches in processing, synthesis, characterization, and mechanics modeling. In addition to traditional fiber-/particulate-reinforced engineering composites, it encourages submissions on composites with exceptional physical, mechanical, and fracture properties, as well as those with unique functions and significant application potential. This includes biomimetic and bio-inspired composites for biomedical applications, functional nano-composites for thermal management and energy applications, and composites designed for extreme service environments.