Study on effects of anti-freeze protein and polyvinyl alcohol on the production and flow behavior of ice slurry

Ice slurry is a promising functional fluid with high thermal energy density and high heat transfer rate. However, the agglomeration of the ice particles in flowing ice slurry can cause blocking of tubes. In this study, anti-freeze protein (AFP) and polyvinyl alcohol (PVA) were selected as additives to prevent the agglomeration of ice particles in ice slurry. Ice slurry was generated using the release of the supercooled state of 3 mass% NaCl solution containing the additives. The size of the ice particles in the ice slurry was observed, and the average area of the ice particles was evaluated to reveal the effects of the additives on the ice particle size. Furthermore, the flow behavior of the ice slurry in a tube was observed, and the effects of the additives on the flow behavior and prevention of the agglomeration of the ice particles were evaluated experimentally. It was found that the average area decreased with increasing concentration of the additives, and the effect of AFP on the average area was particularly significant. In the case of without the additives, the ice particles flowed in the tube while the ice particles agglomerated. On the other hand, the ice particles in the ice slurry with the additives flowed without agglomeration in the tube, especially in the case of AFP addition. It was found that AFP prevented the agglomeration of the ice particles in the ice slurry flow. Moreover, the ice slurries with AFP show the significant tendency for pseudo-plastic fluid.