腐蚀试验期间天然气管道介质流动模式模拟

IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Inorganic Materials Pub Date : 2024-07-30 DOI:10.1134/s0020168524700158
R. K. Vagapov, K. A. Ibatullin, V. V. Yarkovoy
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引用次数: 0

摘要

摘要 在通过管道生产和运输的天然气和天然气凝析油中,腐蚀性二氧化碳或硫化氢浓度的升高会对钢制基础设施的内表面造成严重的腐蚀破坏。本文介绍了沿天然气管道下部的介质流腐蚀效应的研究结果,介质流可能呈现动态、间歇或静态特征。在测试过程中,评估了介质流对 U 型电池的动态影响,以及水相在气泡测试过程中对管道壁的永久影响。天然气管道内可变湿润条件的建模表明,这种条件是典型的,在生产和运输原料天然气到天然气处理和净化场所时会出现。我们模拟了天然气管道内的危险操作因素:水环境成分、温度和腐蚀性气体含量。在确定钢材对局部腐蚀(点蚀、宽而浅的腐蚀坑)的抗性时,我们发现,在二氧化碳和硫化氢的侵蚀条件下,钢材的局部和整体腐蚀发展速度可达 2-3 毫米/年。此外,研究还表明,使用缓蚀剂保护天然气设施的设备和管道可以有效防止内部腐蚀过程的发生。所获得的结果可用于评估运行介质的腐蚀活性,并选择最行之有效的缓蚀剂在气田进行试点测试。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Simulation of the Modes of Medium Flow Movement through a Gas Pipeline during Corrosion Tests

Abstract

Elevated concentrations of corrosive carbon dioxide or hydrogen sulfide in gas and gas condensate both produced and transported through pipelines lead to serious corrosion damage to the internal surfaces of steel infrastructure facilities. The paper presents the results of studying the corrosive effect of the medium flow along the lower component of the gas pipeline, which can exhibit a dynamic, intermittent, or static character. During testing, the effect of both dynamic conditions of the medium flow on the U-shaped cell and static conditions of the permanent impact of the aqueous phase on the pipeline wall during the bubble test was evaluated. Modeling of variable wetting conditions inside the gas pipeline showed that such conditions are typical and occur upon production and transportation of raw gas to the places of gas processing and purification. We have simulated dangerous operational factors that occur inside the gas pipeline: the composition of the aquatic environment, temperature, and the content of corrosive gases. When determining the resistance of steels to local forms of corrosion (pitting, wide and shallow corrosion pits), we revealed that the rate of developing local and general corrosion of steel in aggressive carbon dioxide and hydrogen sulfide conditions can reach 2–3 mm/year. In addition, it has been shown that the use of corrosion inhibitors for protecting the equipment and pipelines of gas facilities can effectively prevent the occurrence of internal corrosion processes. The results obtained can be used in assessing the corrosion activity of operating media and selecting the most proven corrosion inhibitors for pilot testing at gas fields.

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来源期刊
Inorganic Materials
Inorganic Materials 工程技术-材料科学:综合
CiteScore
1.40
自引率
25.00%
发文量
80
审稿时长
3-6 weeks
期刊介绍: Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.
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