掺杂 2 2-8% BaZrO3 的 YBa2Cu3O7-x 纳米复合材料中用于增强引脚的 Ca 修复 BaZrO3 纳米棒/YBa2Cu3O7-x 界面

Judy Wu, Mohan Panth, Victor Ogunjimi, Mary Ann Sebastian, Di Zhang, Timothy Haugan, Haiyan Wang
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摘要

在掺杂了 BZO 的 YaBa2Cu3O7-x (BZO/YBCO)纳米复合薄膜中,通过应变介导的自组装形成的 C 轴排列的 BaZrO3(BZO)纳米棒可以为量子化磁涡旋提供强大的固定作用。虽然 BZO/YBCO 晶格失配产生的应变在 BZO 纳米棒的成核和演化过程中起着关键作用,但它也会导致 BZO/YBCO 界面的高度缺陷,从而降低 BZO 纳米棒的引脚效率。这项工作报告了一项最新研究,即在 BZO 纳米棒生长过程中使用掺杂钙元素动态修复 BZO/YBCO 界面,从而探测 BZO/YBCO 界面对 BZO 纳米棒引脚效率的影响。在 BZO 掺杂量为 2-8 vol.% 的范围内,观察到 BZO 纳米棒的引脚效率显著提高。在界面修复后的 6 Vol.% BZO/YBCO 纳米复合材料中,9.0 T 和 65-77 K 下的临界电流密度峰值提高了 5 倍。这一结果不仅说明了 BZO/YBCO 界面在引脚效率中的极端重要性,而且还提供了实现这种界面的简便方案,以恢复 BZO 纳米棒的原始引脚效率。
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Ca-repaired BaZrO3 nanorods/YBa2Cu3O7-x interface for enhanced pinning in YBa2Cu3O7-x nanocomposites with 2-8% BaZrO3 doping
C-axis aligned BaZrO3 (BZO) nanorods formed via strain-mediated self-assembly in BZO-doped YaBa2Cu3O7-x (BZO/YBCO) nanocomposite films can provide strong pinning to the quantized magnetic vortices. While the strain initiated from the BZO/YBCO lattice mismatch plays a critical role in nucleation and evolution of the BZO nanorods, it also leads to a highly defective BZO/YBCO interface and hence reduced pinning efficiency of BZO nanorods. This work reports a recent study in probing the effect of BZO/YBCO interface on the pinning efficiency of the BZO nanorods as the interface is repaired dynamically during the BZO nanorod growth using Ca doping. Within the BZO doping range of 2-8 vol.%, significantly enhanced pinning efficiency of the BZO nanorods have been observed. A peak enhancement up to five-fold of critical current density at 9.0 T and 65-77 K has been obtained in the 6 vol.% BZO/YBCO nanocomposites after the interface repair. This result not only illustrates the critical importance of the BZO/YBCO interface in the pinning efficiency, but also provides a facile scheme to achieve such an interface to restore the pristine pinning efficiency of the BZO nanorods.
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