利用废 PET 水瓶生产智能聚合物共混长丝:热记忆和形状记忆行为研究

IF 2.8 4区 工程技术 Q2 POLYMER SCIENCE Macromolecular Research Pub Date : 2024-08-09 DOI:10.1007/s13233-024-00303-4
Ecem Özen Öner, Mediha Kök, Mustafa Ersin Pekdemir, Ercan Aydoğmuş, Sinan Saydam, Yıldırım Aydoğdu
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引用次数: 0

摘要

废弃的(聚对苯二甲酸乙二醇酯)(PET)水瓶是自然界中最常见的塑料废物之一。这些塑料垃圾在被释放到自然界后几百年内就会消失。因此,它造成了严重的环境污染。因此,使这些废物可重复利用是很重要的。本研究旨在为重用文献提供一个新的视角。以废PET为原料制备智能共混聚合物,具有很高的应用价值。因此,本研究将废旧聚合物PET与智能聚合物PLA共混制成长丝共混物。用差示扫描量热法(DSC)和热重分析法(TGA)分析了共混物的热性能,用衰减全反射-傅里叶变换红外光谱(ATR-FTIR)测定了化学键结构,并进行了形状记忆测试以确定共混物是否具有智能材料性能。研究结果表明,共混长丝的热稳定性随聚合物配比的不同而变化,共混物的性质为非混相聚合物共混物。还发现聚合物共混物具有形状记忆特性。图形抽象
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Production of smart polymer blend filament from waste PET obtained water bottles: investigation of thermal and shape memory behavior

Waste (polyethylene terephthalate) (PET) water bottles are among the most common plastic wastes in nature. These plastic wastes disappear within hundreds of years after they are released into nature. Therefore, it causes serious environmental pollution. Therefore, it is important to make these wastes reusable. This study aims to bring a new perspective to the reuse literature. It is aimed to produce smart polymer blend from waste PET, which is highly demanded and important in practical applications. Therefore, in this study, waste polymer PET was blended with smart polymer PLA into filament blends. The thermal properties of the blends were analysed by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA), chemical bond structures were determined by Attenuated Total Reflectance-Fourier transform infrared spectroscopy (ATR-FTIR spectroscopy) and shape memory tests were performed to determine whether the blends exhibit smart material properties. As a result of this study, it was observed that the thermal stability of the blended filaments varied according to the polymer ratio and the blend was characterized as an immiscible polymer blend. It was also found that the polymer blends exhibit shape memory properties.

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来源期刊
Macromolecular Research
Macromolecular Research 工程技术-高分子科学
CiteScore
4.70
自引率
8.30%
发文量
100
审稿时长
1.3 months
期刊介绍: Original research on all aspects of polymer science, engineering and technology, including nanotechnology Presents original research articles on all aspects of polymer science, engineering and technology Coverage extends to such topics as nanotechnology, biotechnology and information technology The English-language journal of the Polymer Society of Korea Macromolecular Research is a scientific journal published monthly by the Polymer Society of Korea. Macromolecular Research publishes original researches on all aspects of polymer science, engineering, and technology as well as new emerging technologies using polymeric materials including nanotechnology, biotechnology, and information technology in forms of Articles, Communications, Notes, Reviews, and Feature articles.
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