{"title":"杂草植物(Pouzolzia zeylanica L.)可持续抑制剂在 0.5 M HCl 酸性介质中对 SS-410 表面的缓蚀效果评估","authors":"Vibha Tripathi , Dwarika Prasad , Rajnish Maithani , Brahim El Ibrahimii","doi":"10.1016/j.jtice.2024.105693","DOIUrl":null,"url":null,"abstract":"<div><h3>Background</h3><p>The research has looked into the potential of plant extracts as natural corrosion inhibitors as an alternative to synthetic ones. The study aims to investigate the ability of the weed plant <em>Pouzolzia zeylanica</em> L. extract (<em>PZE</em>) to prevent corrosion of stainless steel-410 in a 0.5 M HCl acidic medium.</p></div><div><h3>Method</h3><p>In this work, the leaf extract of <em>PZE</em> is prepared in water, and the functional activity of the prepared <em>PZ</em> water extract (<em>PZE)</em>is evaluated using various techniques. Both electrochemical and gravimetric techniques are employed in this study. The inhibitor from <em>PZ</em> inhibits the anodic region on the SS-410 surface active sites through straightforward adsorption. Experimental techniques such as UV–visible spectroscopy, FTIR, LC-MS, SEM, AFM, EDX, EIS, and computational studies demonstrate the formation of protective layers under inhibiting conditions. The gravimetric data confirms monolayer adsorption, following the Langmuir adsorption isotherm.</p></div><div><h3>Significant findings</h3><p>The data obtained demonstrate that when SS-410 is immersed directly in a corrosive solution containing dissolved inhibitor molecules, it effectively prevents corrosion. Therefore, increasing the concentration of this chemical improves its inhibitory efficiency. Indeed, the PZ inhibitor achieved a favourable experimental outcome with an efficacy of 95 % at 400 mg/L in 0.5 M HCl. Based on polarization analysis, the corrosion inhibitor exhibits anodic nature for SS-410 in 0.5 M HCl.</p></div>","PeriodicalId":381,"journal":{"name":"Journal of the Taiwan Institute of Chemical Engineers","volume":"165 ","pages":"Article 105693"},"PeriodicalIF":5.5000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Corrosion inhibition assessment of a sustainable inhibitor from the weed plant (Pouzolzia zeylanica L.) on SS-410 surface in 0.5 M HCl acidic medium\",\"authors\":\"Vibha Tripathi , Dwarika Prasad , Rajnish Maithani , Brahim El Ibrahimii\",\"doi\":\"10.1016/j.jtice.2024.105693\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><h3>Background</h3><p>The research has looked into the potential of plant extracts as natural corrosion inhibitors as an alternative to synthetic ones. The study aims to investigate the ability of the weed plant <em>Pouzolzia zeylanica</em> L. extract (<em>PZE</em>) to prevent corrosion of stainless steel-410 in a 0.5 M HCl acidic medium.</p></div><div><h3>Method</h3><p>In this work, the leaf extract of <em>PZE</em> is prepared in water, and the functional activity of the prepared <em>PZ</em> water extract (<em>PZE)</em>is evaluated using various techniques. Both electrochemical and gravimetric techniques are employed in this study. The inhibitor from <em>PZ</em> inhibits the anodic region on the SS-410 surface active sites through straightforward adsorption. Experimental techniques such as UV–visible spectroscopy, FTIR, LC-MS, SEM, AFM, EDX, EIS, and computational studies demonstrate the formation of protective layers under inhibiting conditions. The gravimetric data confirms monolayer adsorption, following the Langmuir adsorption isotherm.</p></div><div><h3>Significant findings</h3><p>The data obtained demonstrate that when SS-410 is immersed directly in a corrosive solution containing dissolved inhibitor molecules, it effectively prevents corrosion. Therefore, increasing the concentration of this chemical improves its inhibitory efficiency. Indeed, the PZ inhibitor achieved a favourable experimental outcome with an efficacy of 95 % at 400 mg/L in 0.5 M HCl. Based on polarization analysis, the corrosion inhibitor exhibits anodic nature for SS-410 in 0.5 M HCl.</p></div>\",\"PeriodicalId\":381,\"journal\":{\"name\":\"Journal of the Taiwan Institute of Chemical Engineers\",\"volume\":\"165 \",\"pages\":\"Article 105693\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-08-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Taiwan Institute of Chemical Engineers\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1876107024003511\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Taiwan Institute of Chemical Engineers","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1876107024003511","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
摘要
背景这项研究探讨了植物提取物作为天然缓蚀剂替代合成缓蚀剂的潜力。本研究旨在调查杂草植物 Pouzolzia zeylanica L. 提取物(PZE)在 0.5 M HCl 酸性介质中防止不锈钢-410 腐蚀的能力。本研究采用了电化学和重量测量两种技术。PZ 中的抑制剂通过直接吸附作用抑制了 SS-410 表面活性部位上的阳极区。紫外可见光谱、傅立叶变换红外光谱、LC-MS、SEM、AFM、EDX、EIS 等实验技术和计算研究证明了在抑制条件下保护层的形成。重要发现所获得的数据表明,将 SS-410 直接浸入含有溶解抑制剂分子的腐蚀性溶液中,可以有效防止腐蚀。因此,增加该化学品的浓度可提高其抑制效率。事实上,PZ 抑制剂在 0.5 M HCl 溶液中的浓度为 400 mg/L 时,抑制效果达到 95%,取得了良好的实验结果。根据极化分析,该缓蚀剂在 0.5 M HCl 中对 SS-410 呈阳极性质。
Corrosion inhibition assessment of a sustainable inhibitor from the weed plant (Pouzolzia zeylanica L.) on SS-410 surface in 0.5 M HCl acidic medium
Background
The research has looked into the potential of plant extracts as natural corrosion inhibitors as an alternative to synthetic ones. The study aims to investigate the ability of the weed plant Pouzolzia zeylanica L. extract (PZE) to prevent corrosion of stainless steel-410 in a 0.5 M HCl acidic medium.
Method
In this work, the leaf extract of PZE is prepared in water, and the functional activity of the prepared PZ water extract (PZE)is evaluated using various techniques. Both electrochemical and gravimetric techniques are employed in this study. The inhibitor from PZ inhibits the anodic region on the SS-410 surface active sites through straightforward adsorption. Experimental techniques such as UV–visible spectroscopy, FTIR, LC-MS, SEM, AFM, EDX, EIS, and computational studies demonstrate the formation of protective layers under inhibiting conditions. The gravimetric data confirms monolayer adsorption, following the Langmuir adsorption isotherm.
Significant findings
The data obtained demonstrate that when SS-410 is immersed directly in a corrosive solution containing dissolved inhibitor molecules, it effectively prevents corrosion. Therefore, increasing the concentration of this chemical improves its inhibitory efficiency. Indeed, the PZ inhibitor achieved a favourable experimental outcome with an efficacy of 95 % at 400 mg/L in 0.5 M HCl. Based on polarization analysis, the corrosion inhibitor exhibits anodic nature for SS-410 in 0.5 M HCl.
期刊介绍:
Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.