Nasir Ahamed N , H.C. Manjunatha , Y.S. Vidya , R. Munirathnam , S. Manjunatha , M. Shivanna , Sahana R , Jayadev Pattar
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引用次数: 0
摘要
采用溶液燃烧法合成了铬酸钇(YCrO4)纳米粒子(YCNPs),并使用绿色提取物(印度楝树叶提取物)作为还原剂。得到的 NPs 可在 600 °C 煅烧。PXRD 图谱显示出布拉格反射,证实 YC NPs 形成了纯正的四方相,属于空间群 I 41/a m d:1。表面形貌显示出较小的、不规则尺寸和形状的 NPs,具有孔隙和空洞,这是溶液燃烧合成的特征。紫外-可见光谱分析证实了各种吸光度峰。根据伍德和陶克曲线图确定的能带隙为 3.08 eV。傅立叶变换红外光谱分析证实了样品中存在特定的官能团。电化学分析表明,在 10 mV/s 至 50 mV/s 的扫描范围内,比电容范围为 61.52 至 40.18 F/g,这是由于扫描速率增加会限制离子向更深孔隙的扩散,从而降低比电容,有利于与表面的相互作用,从而降低活性位点的利用率和整体电容。总之,这些研究结果表明,YCNPs 有望在先进的储能设备中得到实际应用。
Electrochemical analysis of Yttrium chromate nanoparticles synthesized via green mediated combustion route
Yttrium Chromate (YCrO4) nanoparticles (YCNPs) were synthesized using a solution combustion method with a green extract (NeemLeaves extract as a reducing agent. The as-obtained NPs are allowed for calcination at 600 °C. The PXRD pattern showed Bragg reflections confirming the formation of a pure tetragonal phase of YC NPs belonging to the space group I 41/a m d:1. without impurity peaks. The surface morphology revealed smaller, irregularly sized, and shaped NPs with pores and hollows which is the characteristic of solution combustion synthesis. UV–visible spectroscopic analysis confirmed the various absorbance peaks. The energy band gap, determined from Wood and Tauc's plot, was 3.08 eV. FTIR analysis confirmed the presence of specific functional groups in the sample. Electrochemical analysis revealed a specific capacitance range of 61.52 to 40.18 F/g within the scan range of 10 mV/s to 50 mV/s which is due to Increasing scan rate reduces specific capacitance by limiting ion diffusion into deeper pores, favoring interaction with the surface, thus decreasing utilization of active sites and overall capacitance. Collectively, these findings suggest that YCNPs hold promise for practical applications in advanced energy storage devices.