{"title":"关于单一和多种植物化学物质对促进 ZrO2 纳米粒子绿色合成的影响的综合研究","authors":"","doi":"10.1016/j.nanoso.2024.101303","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, we conducted an extensive study of fabrication of ZrO<sub>2</sub> NPs mediated by one type and mixture of plant secondary metabolites in three different calcination temperatures to investigate the influence of the type and concentration of phytochemicals in the green synthesis of nanoparticles. Gallic acid, which is a phenolic compound with strong antioxidant activity, enables to stabilize particle surfaces thereby preventing aggregation and agglomeration of particles. GC-MS and LC-HRMS analysis reveal that polar leaf extract as mixture of secondary metabolites contains ten volatile and forty-one polar compounds, respectively. The TGA/DTG experiments demonstrate that the type and concentration of secondary metabolites substantially influence the crystal formation and ultimately impact the size, morphology, surface texture, and acidity of ZrO<sub>2</sub> NPs. Well crystalline and homogenous ZrO<sub>2</sub> nanospheres were successfully formed by using gallic acid and polar leaf extract as biofuels with crystal size ranging from 6.30–61.92 nm and average particle size ranging from 26–39 nm. The green prepared-ZrO<sub>2</sub> NPs possess surface area from 6.37 to 76.02 m²/g, pore volume from 0.049 to 0.392 cm³/g, pore diameter from 4.17 up to 50.75 nm, and acidity from 0.0574 to 2.0966 mmol/g. Apart from that, this research also indicates that applied calcination temperature affects the features of the nanoparticles mentioned above, except for morphology.</p></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":null,"pages":null},"PeriodicalIF":5.4500,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A comprehensive study on the influence of single and multiple phytochemicals in facilitating green synthesis of ZrO2 nanoparticles\",\"authors\":\"\",\"doi\":\"10.1016/j.nanoso.2024.101303\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, we conducted an extensive study of fabrication of ZrO<sub>2</sub> NPs mediated by one type and mixture of plant secondary metabolites in three different calcination temperatures to investigate the influence of the type and concentration of phytochemicals in the green synthesis of nanoparticles. Gallic acid, which is a phenolic compound with strong antioxidant activity, enables to stabilize particle surfaces thereby preventing aggregation and agglomeration of particles. GC-MS and LC-HRMS analysis reveal that polar leaf extract as mixture of secondary metabolites contains ten volatile and forty-one polar compounds, respectively. The TGA/DTG experiments demonstrate that the type and concentration of secondary metabolites substantially influence the crystal formation and ultimately impact the size, morphology, surface texture, and acidity of ZrO<sub>2</sub> NPs. Well crystalline and homogenous ZrO<sub>2</sub> nanospheres were successfully formed by using gallic acid and polar leaf extract as biofuels with crystal size ranging from 6.30–61.92 nm and average particle size ranging from 26–39 nm. The green prepared-ZrO<sub>2</sub> NPs possess surface area from 6.37 to 76.02 m²/g, pore volume from 0.049 to 0.392 cm³/g, pore diameter from 4.17 up to 50.75 nm, and acidity from 0.0574 to 2.0966 mmol/g. Apart from that, this research also indicates that applied calcination temperature affects the features of the nanoparticles mentioned above, except for morphology.</p></div>\",\"PeriodicalId\":397,\"journal\":{\"name\":\"Nano-Structures & Nano-Objects\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.4500,\"publicationDate\":\"2024-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano-Structures & Nano-Objects\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352507X24002142\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Physics and Astronomy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano-Structures & Nano-Objects","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352507X24002142","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Physics and Astronomy","Score":null,"Total":0}
A comprehensive study on the influence of single and multiple phytochemicals in facilitating green synthesis of ZrO2 nanoparticles
In this work, we conducted an extensive study of fabrication of ZrO2 NPs mediated by one type and mixture of plant secondary metabolites in three different calcination temperatures to investigate the influence of the type and concentration of phytochemicals in the green synthesis of nanoparticles. Gallic acid, which is a phenolic compound with strong antioxidant activity, enables to stabilize particle surfaces thereby preventing aggregation and agglomeration of particles. GC-MS and LC-HRMS analysis reveal that polar leaf extract as mixture of secondary metabolites contains ten volatile and forty-one polar compounds, respectively. The TGA/DTG experiments demonstrate that the type and concentration of secondary metabolites substantially influence the crystal formation and ultimately impact the size, morphology, surface texture, and acidity of ZrO2 NPs. Well crystalline and homogenous ZrO2 nanospheres were successfully formed by using gallic acid and polar leaf extract as biofuels with crystal size ranging from 6.30–61.92 nm and average particle size ranging from 26–39 nm. The green prepared-ZrO2 NPs possess surface area from 6.37 to 76.02 m²/g, pore volume from 0.049 to 0.392 cm³/g, pore diameter from 4.17 up to 50.75 nm, and acidity from 0.0574 to 2.0966 mmol/g. Apart from that, this research also indicates that applied calcination temperature affects the features of the nanoparticles mentioned above, except for morphology.
期刊介绍:
Nano-Structures & Nano-Objects is a new journal devoted to all aspects of the synthesis and the properties of this new flourishing domain. The journal is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. The journal is focused on the objects rather than on their applications. However, the research for new applications of original nano-structures & nano-objects in various fields such as nano-electronics, energy conversion, catalysis, drug delivery and nano-medicine is also welcome. The scope of Nano-Structures & Nano-Objects involves: -Metal and alloy nanoparticles with complex nanostructures such as shape control, core-shell and dumbells -Oxide nanoparticles and nanostructures, with complex oxide/metal, oxide/surface and oxide /organic interfaces -Inorganic semi-conducting nanoparticles (quantum dots) with an emphasis on new phases, structures, shapes and complexity -Nanostructures involving molecular inorganic species such as nanoparticles of coordination compounds, molecular magnets, spin transition nanoparticles etc. or organic nano-objects, in particular for molecular electronics -Nanostructured materials such as nano-MOFs and nano-zeolites -Hetero-junctions between molecules and nano-objects, between different nano-objects & nanostructures or between nano-objects & nanostructures and surfaces -Methods of characterization specific of the nano size or adapted for the nano size such as X-ray and neutron scattering, light scattering, NMR, Raman, Plasmonics, near field microscopies, various TEM and SEM techniques, magnetic studies, etc .