{"title":"通过离散断面法建立碳质颗粒形态、多分散性和纳米结构的动力学模型","authors":"","doi":"10.1016/j.combustflame.2024.113697","DOIUrl":null,"url":null,"abstract":"<div><p>Carbon nanoparticle (CNP) formation from hydrocarbons combustion is of high interest not only for the study of pollutant (soot) emissions, but, above all, in the area of advanced materials. CNP optical and electronical properties, relevant for practical applications, significantly change with their size, morphology, and nanostructure. This work extends a detailed soot kinetic model, based on the discrete sectional approach, to explicitly incorporate the description of CNP polydispersity, maintaining the CHEMKIN-like format. The model considers various nanosized primary particles, generated from liquid-like counterparts through the carbonization process, which successively grow or aggregate forming fractal structures. The model is validated against experimental measurements from the literature including CNP volume fraction, several morphological characteristics, number density and particle H/C ratio. Data are taken from 19 laminar flames, in different configurations (counterflow diffusion flames, premixed flat flames established on the McKenna-type burner and burner-stabilized stagnation flames) and over a wide range of operating conditions (P=1–10 atm, T<sub>max</sub>=1556-2264 K). The model captures the measured trends of all the analyzed CNP properties as a function of equivalence ratio, residence time and fuel type in premixed flames, and pressure and strain rate in counterflow flames. Model deviations from the experiments are discussed, also in comparison with other state-of-the-art soot models based on different approaches. Sensitivity analyses are performed on carbonization, coalescence, and aggregation rates, which have the largest impact on CNP morphology and are characterized by larger uncertainty compared to elementary chemical pathways.</p></div>","PeriodicalId":280,"journal":{"name":"Combustion and Flame","volume":null,"pages":null},"PeriodicalIF":5.8000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0010218024004061/pdfft?md5=e34fdf45dcdfa911f579fe68ea07ff83&pid=1-s2.0-S0010218024004061-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Kinetic modeling of carbonaceous particle morphology, polydispersity and nanostructure through the discrete sectional approach\",\"authors\":\"\",\"doi\":\"10.1016/j.combustflame.2024.113697\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Carbon nanoparticle (CNP) formation from hydrocarbons combustion is of high interest not only for the study of pollutant (soot) emissions, but, above all, in the area of advanced materials. CNP optical and electronical properties, relevant for practical applications, significantly change with their size, morphology, and nanostructure. This work extends a detailed soot kinetic model, based on the discrete sectional approach, to explicitly incorporate the description of CNP polydispersity, maintaining the CHEMKIN-like format. The model considers various nanosized primary particles, generated from liquid-like counterparts through the carbonization process, which successively grow or aggregate forming fractal structures. The model is validated against experimental measurements from the literature including CNP volume fraction, several morphological characteristics, number density and particle H/C ratio. Data are taken from 19 laminar flames, in different configurations (counterflow diffusion flames, premixed flat flames established on the McKenna-type burner and burner-stabilized stagnation flames) and over a wide range of operating conditions (P=1–10 atm, T<sub>max</sub>=1556-2264 K). The model captures the measured trends of all the analyzed CNP properties as a function of equivalence ratio, residence time and fuel type in premixed flames, and pressure and strain rate in counterflow flames. Model deviations from the experiments are discussed, also in comparison with other state-of-the-art soot models based on different approaches. Sensitivity analyses are performed on carbonization, coalescence, and aggregation rates, which have the largest impact on CNP morphology and are characterized by larger uncertainty compared to elementary chemical pathways.</p></div>\",\"PeriodicalId\":280,\"journal\":{\"name\":\"Combustion and Flame\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-08-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0010218024004061/pdfft?md5=e34fdf45dcdfa911f579fe68ea07ff83&pid=1-s2.0-S0010218024004061-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Combustion and Flame\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010218024004061\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Combustion and Flame","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010218024004061","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Kinetic modeling of carbonaceous particle morphology, polydispersity and nanostructure through the discrete sectional approach
Carbon nanoparticle (CNP) formation from hydrocarbons combustion is of high interest not only for the study of pollutant (soot) emissions, but, above all, in the area of advanced materials. CNP optical and electronical properties, relevant for practical applications, significantly change with their size, morphology, and nanostructure. This work extends a detailed soot kinetic model, based on the discrete sectional approach, to explicitly incorporate the description of CNP polydispersity, maintaining the CHEMKIN-like format. The model considers various nanosized primary particles, generated from liquid-like counterparts through the carbonization process, which successively grow or aggregate forming fractal structures. The model is validated against experimental measurements from the literature including CNP volume fraction, several morphological characteristics, number density and particle H/C ratio. Data are taken from 19 laminar flames, in different configurations (counterflow diffusion flames, premixed flat flames established on the McKenna-type burner and burner-stabilized stagnation flames) and over a wide range of operating conditions (P=1–10 atm, Tmax=1556-2264 K). The model captures the measured trends of all the analyzed CNP properties as a function of equivalence ratio, residence time and fuel type in premixed flames, and pressure and strain rate in counterflow flames. Model deviations from the experiments are discussed, also in comparison with other state-of-the-art soot models based on different approaches. Sensitivity analyses are performed on carbonization, coalescence, and aggregation rates, which have the largest impact on CNP morphology and are characterized by larger uncertainty compared to elementary chemical pathways.
期刊介绍:
The mission of the journal is to publish high quality work from experimental, theoretical, and computational investigations on the fundamentals of combustion phenomena and closely allied matters. While submissions in all pertinent areas are welcomed, past and recent focus of the journal has been on:
Development and validation of reaction kinetics, reduction of reaction mechanisms and modeling of combustion systems, including:
Conventional, alternative and surrogate fuels;
Pollutants;
Particulate and aerosol formation and abatement;
Heterogeneous processes.
Experimental, theoretical, and computational studies of laminar and turbulent combustion phenomena, including:
Premixed and non-premixed flames;
Ignition and extinction phenomena;
Flame propagation;
Flame structure;
Instabilities and swirl;
Flame spread;
Multi-phase reactants.
Advances in diagnostic and computational methods in combustion, including:
Measurement and simulation of scalar and vector properties;
Novel techniques;
State-of-the art applications.
Fundamental investigations of combustion technologies and systems, including:
Internal combustion engines;
Gas turbines;
Small- and large-scale stationary combustion and power generation;
Catalytic combustion;
Combustion synthesis;
Combustion under extreme conditions;
New concepts.