{"title":"利用拉曼光谱结合连续气液分离器对海水中的多组分溶解气体进行快速实时分析","authors":"","doi":"10.1016/j.cjche.2024.04.020","DOIUrl":null,"url":null,"abstract":"<div><p>Rapid and sensitive detection of dissolved gases in seawater is quite essential for the investigation of the global carbon cycle. Large quantities of <em>in situ</em> optical detection techniques showed restricted measurement efficiency, owing to the single gas sensor without the identification ability of multiple gases. In this work, a novel gas−liquid Raman detection method of monitoring the multi-component dissolved gases was proposed based on a continuous gas−liquid separator under a large difference of partial pressure. The limit of detection (LOD) of the gas Raman spectrometer could arrive at about 14 μl·L<sup>−1</sup> for N<sub>2</sub> gas. Moreover, based on the continuous gas−liquid separation process, the detection time of the dissolved gases could be largely decreased to about 200 s compared with that of the traditional detection method (30 min). Effect of equilibrium time on gas−liquid separation process indicated that the extracted efficiency and decay time of these dissolved gases was CO<sub>2</sub> >O<sub>2</sub> >N<sub>2</sub>. In addition, the analysis of the relationship between equilibrium time and flow speed indicated that the decay time decreased with the increase of the flow speed. The validation and application of the developed system presented its great potential for studying the components and spatiotemporal distribution of dissolved gases in seawater.</p></div>","PeriodicalId":9966,"journal":{"name":"Chinese Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rapid and real-time analysis of multi-component dissolved gas in seawater by Raman spectroscopy combined with continuous gas−liquid separator\",\"authors\":\"\",\"doi\":\"10.1016/j.cjche.2024.04.020\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Rapid and sensitive detection of dissolved gases in seawater is quite essential for the investigation of the global carbon cycle. Large quantities of <em>in situ</em> optical detection techniques showed restricted measurement efficiency, owing to the single gas sensor without the identification ability of multiple gases. In this work, a novel gas−liquid Raman detection method of monitoring the multi-component dissolved gases was proposed based on a continuous gas−liquid separator under a large difference of partial pressure. The limit of detection (LOD) of the gas Raman spectrometer could arrive at about 14 μl·L<sup>−1</sup> for N<sub>2</sub> gas. Moreover, based on the continuous gas−liquid separation process, the detection time of the dissolved gases could be largely decreased to about 200 s compared with that of the traditional detection method (30 min). Effect of equilibrium time on gas−liquid separation process indicated that the extracted efficiency and decay time of these dissolved gases was CO<sub>2</sub> >O<sub>2</sub> >N<sub>2</sub>. In addition, the analysis of the relationship between equilibrium time and flow speed indicated that the decay time decreased with the increase of the flow speed. The validation and application of the developed system presented its great potential for studying the components and spatiotemporal distribution of dissolved gases in seawater.</p></div>\",\"PeriodicalId\":9966,\"journal\":{\"name\":\"Chinese Journal of Chemical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1004954124001757\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1004954124001757","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Rapid and real-time analysis of multi-component dissolved gas in seawater by Raman spectroscopy combined with continuous gas−liquid separator
Rapid and sensitive detection of dissolved gases in seawater is quite essential for the investigation of the global carbon cycle. Large quantities of in situ optical detection techniques showed restricted measurement efficiency, owing to the single gas sensor without the identification ability of multiple gases. In this work, a novel gas−liquid Raman detection method of monitoring the multi-component dissolved gases was proposed based on a continuous gas−liquid separator under a large difference of partial pressure. The limit of detection (LOD) of the gas Raman spectrometer could arrive at about 14 μl·L−1 for N2 gas. Moreover, based on the continuous gas−liquid separation process, the detection time of the dissolved gases could be largely decreased to about 200 s compared with that of the traditional detection method (30 min). Effect of equilibrium time on gas−liquid separation process indicated that the extracted efficiency and decay time of these dissolved gases was CO2 >O2 >N2. In addition, the analysis of the relationship between equilibrium time and flow speed indicated that the decay time decreased with the increase of the flow speed. The validation and application of the developed system presented its great potential for studying the components and spatiotemporal distribution of dissolved gases in seawater.
期刊介绍:
The Chinese Journal of Chemical Engineering (Monthly, started in 1982) is the official journal of the Chemical Industry and Engineering Society of China and published by the Chemical Industry Press Co. Ltd. The aim of the journal is to develop the international exchange of scientific and technical information in the field of chemical engineering. It publishes original research papers that cover the major advancements and achievements in chemical engineering in China as well as some articles from overseas contributors.
The topics of journal include chemical engineering, chemical technology, biochemical engineering, energy and environmental engineering and other relevant fields. Papers are published on the basis of their relevance to theoretical research, practical application or potential uses in the industry as Research Papers, Communications, Reviews and Perspectives. Prominent domestic and overseas chemical experts and scholars have been invited to form an International Advisory Board and the Editorial Committee. It enjoys recognition among Chinese academia and industry as a reliable source of information of what is going on in chemical engineering research, both domestic and abroad.