{"title":"应用溶剂型溶解法回收含有受限邻苯二甲酸酯增塑剂的聚氯乙烯地板废料","authors":"","doi":"10.1016/j.resconrec.2024.107889","DOIUrl":null,"url":null,"abstract":"<div><p>The applicability of a new recycling method for extracting contaminants from polymers, dissolution-based recycling, was tested on a polyvinylchloride equipped with diethylhexyl phthalate, benzylbutyl phthalate, di-isobutyl phthalate, di-n‑butyl phthalate, originating from post-consumer flooring waste. Due to European restrictions on these ortho-phthalate diester-based plasticizers, the mechanical recycling of plasticized polyvinylchloride is no longer feasible. In this study, we have shown that dissolution and consecutive purification of the polymer eliminate 99.9 % of diethylhexyl phthalate's initial concentration at the laboratory scale. The impact of different process parameters, e.g., temperature, agitation, and extraction kinetics, have been tested. The findings were transferred to a technical scale of 5 kg/d, using a multi-step extraction in counter-flow mode. An elimination of 99.4 % of diethylhexyl phthalate initial concentration has been achieved, which fulfills legal requirements. These promising results showed the technical feasibility and served as a preliminary stage for further up-scaling to technical readiness level 6.</p></div>","PeriodicalId":21153,"journal":{"name":"Resources Conservation and Recycling","volume":null,"pages":null},"PeriodicalIF":11.2000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0921344924004828/pdfft?md5=8cc930e3a845a2dc2a4519d2e78afdac&pid=1-s2.0-S0921344924004828-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Application of solvent-based dissolution for the recycling of polyvinylchloride flooring waste containing restricted phthalate plasticizers\",\"authors\":\"\",\"doi\":\"10.1016/j.resconrec.2024.107889\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The applicability of a new recycling method for extracting contaminants from polymers, dissolution-based recycling, was tested on a polyvinylchloride equipped with diethylhexyl phthalate, benzylbutyl phthalate, di-isobutyl phthalate, di-n‑butyl phthalate, originating from post-consumer flooring waste. Due to European restrictions on these ortho-phthalate diester-based plasticizers, the mechanical recycling of plasticized polyvinylchloride is no longer feasible. In this study, we have shown that dissolution and consecutive purification of the polymer eliminate 99.9 % of diethylhexyl phthalate's initial concentration at the laboratory scale. The impact of different process parameters, e.g., temperature, agitation, and extraction kinetics, have been tested. The findings were transferred to a technical scale of 5 kg/d, using a multi-step extraction in counter-flow mode. An elimination of 99.4 % of diethylhexyl phthalate initial concentration has been achieved, which fulfills legal requirements. These promising results showed the technical feasibility and served as a preliminary stage for further up-scaling to technical readiness level 6.</p></div>\",\"PeriodicalId\":21153,\"journal\":{\"name\":\"Resources Conservation and Recycling\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":11.2000,\"publicationDate\":\"2024-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0921344924004828/pdfft?md5=8cc930e3a845a2dc2a4519d2e78afdac&pid=1-s2.0-S0921344924004828-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Resources Conservation and Recycling\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921344924004828\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Resources Conservation and Recycling","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921344924004828","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Application of solvent-based dissolution for the recycling of polyvinylchloride flooring waste containing restricted phthalate plasticizers
The applicability of a new recycling method for extracting contaminants from polymers, dissolution-based recycling, was tested on a polyvinylchloride equipped with diethylhexyl phthalate, benzylbutyl phthalate, di-isobutyl phthalate, di-n‑butyl phthalate, originating from post-consumer flooring waste. Due to European restrictions on these ortho-phthalate diester-based plasticizers, the mechanical recycling of plasticized polyvinylchloride is no longer feasible. In this study, we have shown that dissolution and consecutive purification of the polymer eliminate 99.9 % of diethylhexyl phthalate's initial concentration at the laboratory scale. The impact of different process parameters, e.g., temperature, agitation, and extraction kinetics, have been tested. The findings were transferred to a technical scale of 5 kg/d, using a multi-step extraction in counter-flow mode. An elimination of 99.4 % of diethylhexyl phthalate initial concentration has been achieved, which fulfills legal requirements. These promising results showed the technical feasibility and served as a preliminary stage for further up-scaling to technical readiness level 6.
期刊介绍:
The journal Resources, Conservation & Recycling welcomes contributions from research, which consider sustainable management and conservation of resources. The journal prioritizes understanding the transformation processes crucial for transitioning toward more sustainable production and consumption systems. It highlights technological, economic, institutional, and policy aspects related to specific resource management practices such as conservation, recycling, and resource substitution, as well as broader strategies like improving resource productivity and restructuring production and consumption patterns.
Contributions may address regional, national, or international scales and can range from individual resources or technologies to entire sectors or systems. Authors are encouraged to explore scientific and methodological issues alongside practical, environmental, and economic implications. However, manuscripts focusing solely on laboratory experiments without discussing their broader implications will not be considered for publication in the journal.