光化学对中国四川盆地南部冬季灰霾的影响

IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Atmospheric Pollution Research Pub Date : 2024-08-31 DOI:10.1016/j.apr.2024.102300
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引用次数: 0

摘要

近年来,硝酸盐和有机物(OM)已成为冬季灰霾天气中细颗粒物(PM2.5)的主要成分。基于为期一个月(2021 年 12 月 1-31 日)的气态污染物、PM2.5 化学成分及其他相关数据的连续观测,我们研究了位于四川盆地南部的宜宾冬季灰霾形成的主要控制因素。我们的观测结果表明,活动期间发生了两次主要的雾霾事件。硝酸盐和 OM 是 PM2.5 的主要成分,总体贡献率超过 50%。从非污染阶段到污染阶段,硝酸盐和 OM 的浓度分别增加了近四倍和三倍多。此外,在污染期间,高活性挥发性有机化合物的混合比也明显增加,尤其是 OVOCs 混合比增加了 123.83%。PM2.5 浓度与 Ox 浓度呈正相关,当 Ox 浓度超过 80 μg m-3 时,两者之间的关系更为密切。硝酸盐和 Ox 浓度之间以及 OVOCs 和 OM 浓度之间也存在明显的正相关关系。此外,与非污染时期相比,污染时期的光化学老化程度更高。潜在污染源贡献函数(PSCF)分析表明,除本地排放外,区域传输,特别是来自成都和重庆的空气污染物也是造成宜宾冬季灰霾的重要原因。我们的研究结果表明,强烈的大气光化学氧化和明显的光化学作用在很大程度上导致了冬季严重雾霾事件的发生。
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Impact of photochemistry on wintertime haze in the Southern Sichuan Basin, China

Nitrate and organic matters (OM) have become dominant components in fine particles (PM2.5) during winter haze in recent years. Based on continuous observations of gaseous pollutants, the chemical composition of PM2.5, and other relevant data collected over a one-month period (December 1–31, 2021), we investigated the main controlling factors contributing to the formation of wintertime haze in Yibin, located in the southern Sichuan Basin. Our observations reveal that two major haze episodes occurred during the campaign. Nitrate and OM were the dominant components in PM2.5, with an overall contribution of more than 50%. Nitrate and OM concentrations nearly quadrupled and more than tripled, respectively, from the non-pollution phase to the pollution phase. Furthermore, the mixing ratios of high-activity VOCs also noticeably increased during the pollution period, particularly OVOCs mixing ratios increased by 123.83%. PM2.5 concentrations were positively correlated with Ox concentrations, with a stronger relationship observed when Ox concentrations exceeded 80 μg m−3. There were also significant positive correlations between nitrate and Ox concentrations, as well as between OVOCs and OM concentrations. Furthermore, the pollution period showed a much higher degree of photochemical aging compared to the non-pollution period. Potential Source Contribution Function (PSCF) analysis revealed that, in addition to local emissions, regional transport, particularly air pollutants from Chengdu and Chongqing, significantly contributed to winter haze in Yibin. Our findings suggest that intense atmospheric photochemical oxidation and pronounced photochemistry contributed greatly to the occurrence of severe winter haze events.

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来源期刊
Atmospheric Pollution Research
Atmospheric Pollution Research ENVIRONMENTAL SCIENCES-
CiteScore
8.30
自引率
6.70%
发文量
256
审稿时长
36 days
期刊介绍: Atmospheric Pollution Research (APR) is an international journal designed for the publication of articles on air pollution. Papers should present novel experimental results, theory and modeling of air pollution on local, regional, or global scales. Areas covered are research on inorganic, organic, and persistent organic air pollutants, air quality monitoring, air quality management, atmospheric dispersion and transport, air-surface (soil, water, and vegetation) exchange of pollutants, dry and wet deposition, indoor air quality, exposure assessment, health effects, satellite measurements, natural emissions, atmospheric chemistry, greenhouse gases, and effects on climate change.
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