开发耐沸水乳糖基粘合剂和支链 P-N 协同阻燃涂层

IF 4.1 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2024-09-02 DOI:10.1016/j.polymer.2024.127573
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引用次数: 0

摘要

本研究以乳糖和生物质聚氨基化合物(MP)为原料,通过马氏反应、自由基聚合和多重交联网络策略制备了具有优异耐沸水性的乳糖基粘合剂。另一方面,利用所开发的 MP 与氨基三亚甲基膦酸 (ATMP) 反应,构建了支链 P-N 协同阻燃涂层,并将其涂覆在层压复合材料的表层,使其具有阻燃性能。层压复合材料的干剪切强度、3 h热水(63 ℃)湿剪切强度和3 h沸水湿剪切强度分别为2.23 MPa、1.14 MPa和1.02 Mpa,符合GB/T 9846-2015标准的要求(≥0.7 MPa)。综上所述,本研究为制备环保型耐沸水乳糖基胶粘剂和支链P-N协同阻燃涂层提供了可行的方法,可用于高性能木质层压复合材料的制造。
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Developing boiling water resistant lactose-based adhesive and branched P-N synergistic flame retardant coating

In this work, lactose-based adhesive with excellent boiling water resistance was prepared by the Maillard reaction, free radical polymerisation and multiple cross-linking network strategy using lactose and biomass polyamino compound (MP) as raw materials. On the other hand, the branched P-N synergistic flame retardant coating was constructed using the developed MP reacted with aminotrimethylene phosphonic acid (ATMP), which was used to coat the surface layer of laminated composite to give it flame-retardant properties. The dry shear strength, 3 h hot water (63 °C) wet shear strength, and 3 h boiling water wet shear strength of the laminated composite were 2.23 MPa, 1.14 MPa, and 1.02 Mpa, respectively, which were in line with the requirements of GB/T 9846-2015 standard (≥0.7 MPa). In summary, this work provides potential methods for the preparation of environmentally friendly boiling water resistant lactose-based adhesive and branched P-N synergistic flame retardant coating which were used for the construction of high performance wood laminated composites.

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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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