{"title":"电喷纺参数对聚乳酸纳米纤维特性的影响实现高性能生物降解膜的绿色开发","authors":"","doi":"10.1016/j.polymer.2024.127553","DOIUrl":null,"url":null,"abstract":"<div><p>Electro-blow spinning represents a novel and emerging hybridised technology for producing high-quality, large-scale nanofibers. The applied pressure, accompanied by an electric field, functions as a drafting force to generate ultrafine, homogeneous nanofibers. Herein, we utilised a sustainable solvent to produce polylactic acid nanofibers via the electro-blow spinning technique. A parametric study investigating the effect of polymer concentration, pressure, and voltage on the characteristics of the produced nanofibers was thoroughly conducted. The produced nanofibers were tested using scanning electron microscopy, Fourier-transform infrared spectroscopy, differential scanning calorimetry, and tensile test. 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引用次数: 0
摘要
电吹风纺丝是一种生产高质量、大规模纳米纤维的新兴混合技术。施加的压力伴随着电场,可作为牵引力产生超细、均匀的纳米纤维。在此,我们利用一种可持续溶剂,通过电喷纺技术生产聚乳酸纳米纤维。我们对聚合物浓度、压力和电压对纳米纤维特性的影响进行了深入的参数研究。使用扫描电子显微镜、傅立叶变换红外光谱仪、差示扫描量热仪和拉伸试验对制备的纳米纤维进行了测试。研究结果表明,气压在电吹风纺丝过程中起着关键作用,而引入电场则能增强纳米纤维的可纺性和拉伸性。增加施加的压力和电压可使纤维更细,结晶度和机械强度得到改善。然而,过大的压力或电压会导致喷射不稳定,造成纤维熔化或断裂等缺陷。我们的研究表明,要获得均匀且高质量的纳米纤维,最推荐的参数是 10 wt%、5 bar 和 20 kV。此外,我们还使用定制的过滤装置进一步评估了聚乳酸纳米纤维的空气过滤性能,以确定其是否适合用作面罩材料。这些初步研究结果有力地表明,生产出的纳米纤维在医用纺织品的应用中,尤其是在面罩的开发中大有可为。
The effect of electro blow spinning parameters on the characteristics of polylactic acid nanofibers: Towards green development of high-performance biodegradable membrane
Electro-blow spinning represents a novel and emerging hybridised technology for producing high-quality, large-scale nanofibers. The applied pressure, accompanied by an electric field, functions as a drafting force to generate ultrafine, homogeneous nanofibers. Herein, we utilised a sustainable solvent to produce polylactic acid nanofibers via the electro-blow spinning technique. A parametric study investigating the effect of polymer concentration, pressure, and voltage on the characteristics of the produced nanofibers was thoroughly conducted. The produced nanofibers were tested using scanning electron microscopy, Fourier-transform infrared spectroscopy, differential scanning calorimetry, and tensile test. The findings revealed that air pressure plays a crucial role in the electro-blow spinning process, while introducing electric field enhances the spinnability and stretchability of nanofibers. Increasing the applied pressure and voltage led to finer fibres with improved crystallinity and mechanical strength. However, excessive pressure or voltage can cause jet instability, resulting in defects such as fused or broken fibres. Our study suggests that the most recommended parameters for uniform and high-quality nanofibers are 10 wt%, 5 bar, and 20 kV. Moreover, the polylactic acid nanofibers were further evaluated for air filtration performance using a customised filtration setup to determine their suitability as a facemask material. The results indicated a notably high filtration efficiency, reaching up to 98 %, with a corresponding pressure drop between 137 and 163 Pa. These preliminary findings strongly suggest that produced nanofibers are highly promising candidates for medical textile applications, particularly in the development of facemasks.
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.