使用石墨烯纳米片增强含有大量天然坡松的砂浆的抗压强度

IF 4.4 2区 化学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Applied Polymer Materials Pub Date : 2024-09-12 DOI:10.1016/j.conbuildmat.2024.138302
Ayman N. Ababneh , Faris Matalkah , Mohammad Al-Akhras
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引用次数: 0

摘要

高硅酸盐混凝土的凝结时间较长,会抑制早期抗压强度的发展,从而导致施工延迟,限制了其在混凝土行业中的应用。本研究的主要目的是评估石墨烯纳米片(GNPs)在增强含有高浓度天然泊松联的砂浆机械性能方面的有效性。首先,采用相对简单的超声处理工艺,使 GNPs 在混合水中几乎均匀分散,以避免出现限制 GNPs 效率的团聚现象。工程特性测试表明,添加石墨烯纳米微粒的最佳含量分别为粘结剂重量的 0.03% 和 0.01%(水泥替代率分别为 40% 和 60%)时,含有 40% 和 60% 的天然坡缕石(部分替代水泥)的砂浆的抗压强度得到了提高。在固化 7 天、28 天和 56 天时,水泥替代率为 40% 时,抗压强度分别提高了 29.6%、27.4% 和 27.5%;水泥替代率为 60% 时,抗压强度分别提高了 86.3%、23.7% 和 25.8%。扫描电子显微镜研究表明,添加 GNP 使结构致密化,从而提高了灰泥的性能。
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The use of graphene nanoplatelets for enhancement of the compressive strength of mortar containing high-levels of natural Pozzolan

High Pozzolan concrete has an extended setting time and inhibits early-age compressive strength development, which can cause construction delays and limit its application in the concrete industry. The main aim of this study is to evaluate the effectiveness of graphene nanoplatelets (GNPs) in enhancing the mechanical properties of mortar containing high levels of natural Pozzolan. In the beginning, a relatively simple ultrasonication treatment process produced an almost uniform dispersion of GNPs in the mixing water to avoid agglomeration which limits the efficiency of GNPs. Tests on engineering properties indicated that the compressive strength of mortar containing 40 and 60 % natural Pozzolan as a partial replacement of cement was enhanced with the addition of the optimum content of graphene nanoplatelets which was found to be 0.03 % and 0.01 % by weight of binder at 40 % and 60 % cement replacement levels, respectively. The compressive strength was enhanced by 29.6 %, 27.4 %, and 27.5 % at 40 % cement replacement level, and by 86.3 %, 23.7 %, and 25.8 % at 60 % cement replacement level at 7, 28, and 56 days of curing, respectively. SEM investigations indicated that the addition of GNPs densified the structure thus enhancing the performance of mortar.

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来源期刊
CiteScore
7.20
自引率
6.00%
发文量
810
期刊介绍: ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.
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