用于光子、NLO、相位匹配和电子设备的 50 级冲击脉冲对 100 Gy 辐照醋酸锌晶体的合成和研究

IF 1.8 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY ECS Journal of Solid State Science and Technology Pub Date : 2024-08-27 DOI:10.1149/2162-8777/ad6f42
Balamurugapandian N, Suganya K, Hariharasuthan R, Jayanalina T, Swarnalatha V, SenthilKannan K, Manikandan R
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引用次数: 0

摘要

醋酸锌 - ZA 是通过缓慢蒸发的方式在 16-17 天内生长成无色晶体的;在本工作中,ZA-100 Gy 辐照样品的 50 缩放范围的冲击脉冲在物理参考中表示为 ZA-100Gy-50S,ZA-100Gy-50S 的单晶 XRD 数据为 15.ZA-100Gy-50S 的单晶 XRD 数据的 a、b、c 值分别为 15.108、9.254、4.7999(以 Å 为单位),β 值为 99.12°,空间群为 P21/c,体系为单斜;ZA-100Gy-50S 的紫外可见光谱截止波长为 224 nm;带隙(以 eV 为单位)在 Tauc's plot 中为 5.53,在紫外可见数据中为 5.5357 eV。荧光波长给出的能量影响为 2.4047 eV。ZA-100Gy-50S晶体的表面形态影响为小裂纹,无重大缺陷;Z-Scan法测定ZA-100Gy-50S的三阶NLO为13.92×10-6 esu;分析了ZA-100Gy-50S的倍频电路和三倍频电路,分别为输入的2.28倍和3.23倍。基于(111)的显示动作具有红绿蓝填充多边形效果。
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Synthesis, Studies of Shocked Pulse of 50 Scale on 100 Gy Irradiated Zinc Acetate Crystals for Photonic, NLO, Phase-Matching and Electronic Utilities
The Zinc Acetate - ZA is grown in 16–17 days as colorless crystal by slow evaporation manner; in the present work, the shocked pulses of range of 50 scaling of ZA-100 Gy irradiated sample is represented after the pulsed reference of shock waves as ZA-100Gy-50S in physical reference, the single crystalline XRD data of ZA-100Gy-50S is having 15.108, 9.254, 4.7999 of a, b, c values in Å and beta as 99.12° with P21/c as space group and monoclinic as the system; the UV-visible spectral cut-off wavelength for ZA-100Gy-50S is 224 nm; the band gap in eV as 5.53 from Tauc’s plot and is 5.5357 eV from UV-visible data. The Fluorescence wavelength gives the energy impact of 2.4047 eV. The NLO-SHG as 1.34 times than the standard KDP and the phase matching proviso of ZA-100Gy-50S is 93.8 mV The surface morphological impact of ZA-100Gy-50S crystal is with small cracks, no major flaws; the third-order NLO of ZA-100Gy-50S is of 13.92 × 10–6 esu by Z-Scan; the frequency doubling circuit and frequency tripling circuit are analyzed for the ZA-100Gy-50S and are 2.28 times, 3.23 times the input. The (111) based displaying of the display action with Red-Green-Blue filled polygonal effect.
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来源期刊
ECS Journal of Solid State Science and Technology
ECS Journal of Solid State Science and Technology MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
4.50
自引率
13.60%
发文量
455
期刊介绍: The ECS Journal of Solid State Science and Technology (JSS) was launched in 2012, and publishes outstanding research covering fundamental and applied areas of solid state science and technology, including experimental and theoretical aspects of the chemistry and physics of materials and devices. JSS has five topical interest areas: carbon nanostructures and devices dielectric science and materials electronic materials and processing electronic and photonic devices and systems luminescence and display materials, devices and processing.
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