功能性磁响应流动改性剂与磁场协同作用对南阳原油进行改性

Feng Yan, Jionghao Li, Qifu Li, Yunchen Wang, Chaofei Nie, Fan Xiao and Bohong San
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引用次数: 0

摘要

南阳原油属于高蜡原油。其蜡沉积严重,低温流动性差,对含蜡原油的管道运输安全构成重大威胁。为了解决上述问题,我们以甲基丙烯酸甲酯、纳米氧化铁、四乙氧基硅烷和十二烷基三乙氧基硅烷为原料,通过分散聚合制造出了大尺寸聚合物包覆磁性纳米球。在评估了功能性磁响应流动改性剂对南阳原油屈服应力和粘度的影响后,引入磁场效应分析功能性磁响应流动改性剂对粘度和屈服应力的协同效应。结果表明,与 EVA 降凝剂相比,功能性磁响应流动改性剂可大大降低屈服应力和粘度。此外,应用交变磁场可以放大功能磁响应流动改性剂对南阳原油的有利影响。
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Modification of Nanyang crude oil by a functional magnetically responsive flow modifier in synergy with magnetic field
Nanyang crude oil is classified as high wax crude oil. It has severe wax deposition and poor low-temperature fluidity, which pose a major risk to the safety of pipeline transportation of wax-containing crude oil. A large-size polymer-coated magnetic nanosphere was created by dispersion polymerization employing methyl methacrylate, nano-iron oxide, tetraethoxysilane, and dodecyltriethoxysilane as raw materials to address the aforementioned issues.Ethylene-vinyl acetate copolymer was compounded to provide a useful magnetic response flow modifier.Using FTIR and ESEM, the polymer grafted on the iron oxide nanosphere’s surface was shown. After evaluating the functional magnetic response flow modifier’s impact on the yield stress and viscosity of a Nanyang crude oil, the effect of the magnetic field was introduced to analyze the functional magnetic response flow modifier’s synergistic effect on viscosity and yield stress. The results show that the functional magnetic response flow modifier may greatly lower yield stress and viscosity when compared to the EVA pour point depressant. Additionally, applying an alternating magnetic field could amplify the functional magnetic response flow modifier’s beneficial effects on Nanyang crude oil.
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