Hydraulic fracturing in cement mortar subjected to seepage-sulfate coupled attack under varying pH levels

Cement-based structures are prone to hydraulic fracturing in acidic sulfate and seepage environments, posing a significant safety threat to engineering projects. To investigate the impact of pH levels on hydraulic fracturing in cement-based materials under seepage-sulfate coupled attack, hydraulic fracturing test and splitting tensile strength test have been conducted on cement mortar specimens permeated with Na₂SO₄ solution. A mathematical model is developed to establish the relationship between the critical water pressure of hydraulic fracturing and the splitting tensile strength at varying pH levels. The results show that the critical water pressure and splitting tensile strength initially increase and then decrease with the increase in erosion duration under pH levels of 7 and 3, while they continuously decrease with the increase in erosion duration under pH level of 1. Furthermore, the peak values of the critical water pressure and splitting tensile strength gradually diminish, which indicates an increased deterioration in hydraulic fracturing resistance with the decrease in pH value. The relationship between critical water pressure damage coefficient and erosion duration can be accurately described by a quadratic polynomial. Overall, the findings of this study can serve as a useful reference for enhancing the structural performance of cement mortar subjected to seepage-sulfate coupled attack at varying pH levels.