{"title":"设计用于超快激光热疗的多波段蓝色发射 \"绿色 \"等离子纳米复合材料","authors":"Yury Ryabchikov","doi":"10.1039/d4nr03120b","DOIUrl":null,"url":null,"abstract":"Non-toxic nanoscale materials are widely employed for different healthcare applications but their performance is still considerably limited. In this paper, various approaches of the environment-friendly ultrafast laser processing were employed for remodelling IV group semiconductor nanostructures and synthesizing highly-stable (ξ-potential is up to –47 mV) colloidal solutions of plasmonic (525 nm) nanocomposites with a strong size-dependent chemical content. All nanocomposites exhibited a remarkable lamp-excited multi-band blue emission centred at around 420 nm that is considerably (~10-fold for Au-SiC) stronger for nanocomposites prepared by the laser co-fragmentation technique. The latter formed a larger amount of smaller narrowly-dispersed (~ 4 nm for Au-Si) plasmonic nanostructures as compared to the direct laser ablation. Moreover, it also led to a higher content of semiconductor elements (~1.7-fold for Au-Ge) in nanocomposites correlating with a lower (~ 30 %) electrical conductivity. Aqueous colloidal solutions revealed a higher degree (~ 80 %) of the femtosecond laser-induced heating for all nanocomposites formed by the direct laser ablation. These findings highlight the peculiarities of the used laser processing approaches and considerably facilitate designing of specific multi-modal plasmono-fluorescence (biosensing, bioimaging, hyperthermia) nanocomposites with a required performance significantly enlarging the application area of semiconductor nanostructures.","PeriodicalId":92,"journal":{"name":"Nanoscale","volume":null,"pages":null},"PeriodicalIF":5.8000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design of “Green” Plasmonic Nanocomposites with Multi-Band Blue Emission for Ultrafast Laser Hyperthermia\",\"authors\":\"Yury Ryabchikov\",\"doi\":\"10.1039/d4nr03120b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Non-toxic nanoscale materials are widely employed for different healthcare applications but their performance is still considerably limited. In this paper, various approaches of the environment-friendly ultrafast laser processing were employed for remodelling IV group semiconductor nanostructures and synthesizing highly-stable (ξ-potential is up to –47 mV) colloidal solutions of plasmonic (525 nm) nanocomposites with a strong size-dependent chemical content. All nanocomposites exhibited a remarkable lamp-excited multi-band blue emission centred at around 420 nm that is considerably (~10-fold for Au-SiC) stronger for nanocomposites prepared by the laser co-fragmentation technique. The latter formed a larger amount of smaller narrowly-dispersed (~ 4 nm for Au-Si) plasmonic nanostructures as compared to the direct laser ablation. Moreover, it also led to a higher content of semiconductor elements (~1.7-fold for Au-Ge) in nanocomposites correlating with a lower (~ 30 %) electrical conductivity. Aqueous colloidal solutions revealed a higher degree (~ 80 %) of the femtosecond laser-induced heating for all nanocomposites formed by the direct laser ablation. These findings highlight the peculiarities of the used laser processing approaches and considerably facilitate designing of specific multi-modal plasmono-fluorescence (biosensing, bioimaging, hyperthermia) nanocomposites with a required performance significantly enlarging the application area of semiconductor nanostructures.\",\"PeriodicalId\":92,\"journal\":{\"name\":\"Nanoscale\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1039/d4nr03120b\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4nr03120b","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Design of “Green” Plasmonic Nanocomposites with Multi-Band Blue Emission for Ultrafast Laser Hyperthermia
Non-toxic nanoscale materials are widely employed for different healthcare applications but their performance is still considerably limited. In this paper, various approaches of the environment-friendly ultrafast laser processing were employed for remodelling IV group semiconductor nanostructures and synthesizing highly-stable (ξ-potential is up to –47 mV) colloidal solutions of plasmonic (525 nm) nanocomposites with a strong size-dependent chemical content. All nanocomposites exhibited a remarkable lamp-excited multi-band blue emission centred at around 420 nm that is considerably (~10-fold for Au-SiC) stronger for nanocomposites prepared by the laser co-fragmentation technique. The latter formed a larger amount of smaller narrowly-dispersed (~ 4 nm for Au-Si) plasmonic nanostructures as compared to the direct laser ablation. Moreover, it also led to a higher content of semiconductor elements (~1.7-fold for Au-Ge) in nanocomposites correlating with a lower (~ 30 %) electrical conductivity. Aqueous colloidal solutions revealed a higher degree (~ 80 %) of the femtosecond laser-induced heating for all nanocomposites formed by the direct laser ablation. These findings highlight the peculiarities of the used laser processing approaches and considerably facilitate designing of specific multi-modal plasmono-fluorescence (biosensing, bioimaging, hyperthermia) nanocomposites with a required performance significantly enlarging the application area of semiconductor nanostructures.
期刊介绍:
Nanoscale is a high-impact international journal, publishing high-quality research across nanoscience and nanotechnology. Nanoscale publishes a full mix of research articles on experimental and theoretical work, including reviews, communications, and full papers.Highly interdisciplinary, this journal appeals to scientists, researchers and professionals interested in nanoscience and nanotechnology, quantum materials and quantum technology, including the areas of physics, chemistry, biology, medicine, materials, energy/environment, information technology, detection science, healthcare and drug discovery, and electronics.