不同燃烧阶段氨煤共烧的燃料-氮转化机理研究

IF 5.6 2区 工程技术 Q2 ENERGY & FUELS Journal of The Energy Institute Pub Date : 2024-09-19 DOI:10.1016/j.joei.2024.101829
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引用次数: 0

摘要

氨与煤粉共燃可有效减少火力发电的碳排放。然而,氨作为一种无碳燃料,富含大量的氮,增加了高氮氧化物排放的风险。因此,弄清氨在共燃过程中对煤挥发份-N 和煤炭-N 形成 NO 的影响机理,揭示不同燃烧阶段 N 的氧化途径具有重要意义。本研究利用 CHEMKIN 软件进行模拟,研究了氨煤共燃不同燃烧阶段 NO 的生成特征和燃料-N 的转化机理。研究表明,掺氨燃烧促进了煤挥发物的释放和氧化成 NO。在氨煤共烧过程中产生的 NO 总量中,氨耦合煤炭燃烧产生的 NO 所占比例很低。与氨耦合煤燃烧相比,氨耦合煤挥发燃烧产生的 NO 量明显减少。灵敏度分析和生成率(ROP)分析表明,H、OH 和 O 自由基的增加促进了 NO 的形成,而 NHi 自由基在 NO 的还原过程中发挥了重要作用。通过分析氨耦合煤粉、煤挥发物和煤焦在 1400 ℃、10%氨比条件下燃烧产生 NO 的基本路径,可以看出,与氨耦合煤燃烧相比,氨耦合煤挥发物燃烧过程中 NO 形成的主要路径是 VOL→HCN→NCO→NO、CHAR→NO、NH2→HNO→NO。NH2→NH→NO反应路径的比例下降,而NH2→N2、NCN→NCO→N2和NH2→NNH→N2反应路径的比例分别上升,表明分离燃烧促进了NHi自由基对NO的还原,同时抑制了含N成分的氧化。
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Study on fuel-N conversion mechanism of ammonia-coal co-firing at different combustion stages

The co-combustion of ammonia and pulverized coal can effectively reduce the carbon emission of thermal power generation. However, ammonia, as a carbon-free fuel, is rich in large amounts of nitrogen, which increases the risk of high NOx emissions. Therefore, it is important to clarify the influence mechanism of ammonia on the NO formation of coal volatile-N and coal char-N in the co-combustion, and to reveal the N oxidation pathway in different combustion stages.

In this study, simulations were carried out on the CHEMKIN software to investigate the generation characteristics of NO and the transformation mechanism of fuel-N at different combustion stages of ammonia-coal co-firing. The study showed that ammonia-blending combustion promoted the release of coal volatiles and the oxidation to NO. In the total NO generation during the ammonia-coal co-firing, the proportion of NO produced by ammonia-coupled coal char combustion was very low. Compared with ammonia-coupled coal combustion, the amount of NO produced in ammonia-coupled coal volatile combustion was significantly reduced. Sensitivity analysis and rate of production (ROP) analysis indicated that the increase of H, OH, and O free radicals promoted the NO formation, and that NHi free radicals played an important role in the NO reduction. By analyzing the elementary path of NO generated from ammonia-coupled pulverized coal, coal volatiles and coal char combustion at 1400 °C and 10 % ammonia ratio, it can be seen that the main path of NO formation during ammonia-coupled coal volatiles combustion is VOL→HCN→NCO→NO, CHAR→NO, NH2→HNO→NO, compared with ammonia-coupled coal combustion. The proportion of NH2→NH→NO reaction paths decreased, while the proportion of NH2→N2, NCN→NCO→N2, and NH2→NNH→N2 reaction paths increased respectively, indicating that separation combustion promoted the reduction of NO by NHi free radicals while inhibiting the oxidation of N-containing components.

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来源期刊
Journal of The Energy Institute
Journal of The Energy Institute 工程技术-能源与燃料
CiteScore
10.60
自引率
5.30%
发文量
166
审稿时长
16 days
期刊介绍: The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include: Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies Emissions and environmental pollution control; safety and hazards; Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS; Petroleum engineering and fuel quality, including storage and transport Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems Energy storage The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.
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