{"title":"平均功率为 273 兆瓦的紧凑型金属纳米粉体发生器和铜纳米粉体的合成。","authors":"A K Dubey, R Shukla, K Sagar, P Dey, A Sharma","doi":"10.1063/5.0223103","DOIUrl":null,"url":null,"abstract":"<p><p>The synthesis of metal nanoparticles holds significant promise for various applications ranging from electronics to catalysis. Their high specific surface area makes them more applicable in the form of lubricant and sorbent. Some of the metal nano-powders, such as silver, copper, and zinc, possess anti-microbial properties; hence, they are very useful in medical sciences. This paper presents a novel approach to the design and implementation of a compact metal nano-powder generator of 273 MW average power through the electrical explosion of wire method. The design focuses on achieving the automatic and repetitive operation of a compact metal nano-powder generator and minimizing its geometric inductance to achieve a fast rise time current across the exploding wire load. Copper nano-powder is produced with a copper wire of 450 μm thickness and 30 mm length at charging voltages of 8.5, 9.0, and 9.5 kV and achieving a superheat of 1.75, 1.92, and 2.06, respectively. The synthesis process is characterized by a detailed analysis of the copper nano-powder's structural, morphological, and chemical composition using techniques such as x-ray diffraction, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. The particle size distribution studies are performed by adopting the log-normal probability distribution. The results demonstrate the effectiveness of the proposed compact nano-powder generator in producing copper nano-powder with tailored properties suitable for diverse applications.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Compact metal nano-powder generator of 273 MW average power and synthesis of copper nano-powder.\",\"authors\":\"A K Dubey, R Shukla, K Sagar, P Dey, A Sharma\",\"doi\":\"10.1063/5.0223103\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The synthesis of metal nanoparticles holds significant promise for various applications ranging from electronics to catalysis. Their high specific surface area makes them more applicable in the form of lubricant and sorbent. Some of the metal nano-powders, such as silver, copper, and zinc, possess anti-microbial properties; hence, they are very useful in medical sciences. This paper presents a novel approach to the design and implementation of a compact metal nano-powder generator of 273 MW average power through the electrical explosion of wire method. The design focuses on achieving the automatic and repetitive operation of a compact metal nano-powder generator and minimizing its geometric inductance to achieve a fast rise time current across the exploding wire load. Copper nano-powder is produced with a copper wire of 450 μm thickness and 30 mm length at charging voltages of 8.5, 9.0, and 9.5 kV and achieving a superheat of 1.75, 1.92, and 2.06, respectively. The synthesis process is characterized by a detailed analysis of the copper nano-powder's structural, morphological, and chemical composition using techniques such as x-ray diffraction, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. The particle size distribution studies are performed by adopting the log-normal probability distribution. The results demonstrate the effectiveness of the proposed compact nano-powder generator in producing copper nano-powder with tailored properties suitable for diverse applications.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1063/5.0223103\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1063/5.0223103","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
金属纳米粒子的合成为从电子到催化等各种应用带来了巨大的前景。它们的高比表面积使其更适用于润滑剂和吸附剂的形式。一些金属纳米粉体,如银、铜和锌,具有抗微生物特性,因此在医学科学中非常有用。本文介绍了一种新方法,即通过电爆丝法设计和实现平均功率为 273 兆瓦的紧凑型金属纳米粉体发电机。设计的重点是实现紧凑型金属纳米粉体发电机的自动和重复操作,并尽量减小其几何电感,以实现爆炸线负载上的快速上升电流。在充电电压分别为 8.5、9.0 和 9.5 千伏,过热度分别为 1.75、1.92 和 2.06 的条件下,使用厚度为 450 μm、长度为 30 mm 的铜线生产铜纳米粉体。利用 X 射线衍射、扫描电子显微镜和能量色散 X 射线光谱等技术对纳米铜粉的结构、形态和化学成分进行了详细分析,从而确定了合成过程的特征。粒度分布研究采用对数正态概率分布。研究结果表明,所提出的紧凑型纳米粉体发生器能有效地生产出具有定制特性的纳米铜粉,适用于各种不同的应用。
Compact metal nano-powder generator of 273 MW average power and synthesis of copper nano-powder.
The synthesis of metal nanoparticles holds significant promise for various applications ranging from electronics to catalysis. Their high specific surface area makes them more applicable in the form of lubricant and sorbent. Some of the metal nano-powders, such as silver, copper, and zinc, possess anti-microbial properties; hence, they are very useful in medical sciences. This paper presents a novel approach to the design and implementation of a compact metal nano-powder generator of 273 MW average power through the electrical explosion of wire method. The design focuses on achieving the automatic and repetitive operation of a compact metal nano-powder generator and minimizing its geometric inductance to achieve a fast rise time current across the exploding wire load. Copper nano-powder is produced with a copper wire of 450 μm thickness and 30 mm length at charging voltages of 8.5, 9.0, and 9.5 kV and achieving a superheat of 1.75, 1.92, and 2.06, respectively. The synthesis process is characterized by a detailed analysis of the copper nano-powder's structural, morphological, and chemical composition using techniques such as x-ray diffraction, scanning electron microscopy, and energy-dispersive x-ray spectroscopy. The particle size distribution studies are performed by adopting the log-normal probability distribution. The results demonstrate the effectiveness of the proposed compact nano-powder generator in producing copper nano-powder with tailored properties suitable for diverse applications.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.