从硫化物中提取金属的溶解冶金工艺研究

IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Minerals Engineering Pub Date : 2024-09-24 DOI:10.1016/j.mineng.2024.109005
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引用次数: 0

摘要

铜、镍、铁、锌、铅和钼是自然界中常见的重要金属硫化物矿物。其中一些金属还以硫化物形式存在于无光泽和混合硫化物沉淀物(MSP)等中间产品中。通过火法冶金或湿法冶金从硫化物形态中提取这些金属的过程会遇到各种挑战。本研究旨在探索溶胶冶金工艺(溶浸法)作为从硫化物(CuS、Ni3S2、FeS、ZnS、PbS 和 MoS2)中提取这些金属的潜在替代方法的可行性。溶出冶金工艺采用了一系列溶出渗滤系统,如 D2EHPA+MnO2+H2O、由 LIX 84-I+NH4OH+H2O2 组成的氨溶出渗滤、HCl-匀浆 TBP(TBP-HCl)和含有 HCl、FeCl3、ChCl 和 NH4Cl 的 EG(乙二醇)基溶剂。讨论了金属硫化物在每种溶浸体系中的溶浸机理。研究结果与 Eh-pH 图、吉布斯自由能变化、金属离子的溶解特性等热力学工具以及软硬酸碱(HSAB)理论相互印证。利用适当的分析技术(如紫外可见光谱和傅立叶变换红外光谱)对所得浸出液进行分析,为结果提供了更多支持。溶解浸出法与传统的水浸出法进行了比较,结果不相上下,这表明溶解浸出法作为从硫化物中可持续提取这些金属的替代方法是可行的。
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Investigation on solvometallurgical processes for extraction of metals from sulfides
Copper, nickel, iron, zinc, lead, and molybdenum are among the important metals commonly found as sulfide minerals in nature. Some of these metals are also found as sulfides in intermediate products like matte and mixed sulfide precipitates (MSP). The extraction processes of these metals from their sulfide forms through either pyrometallurgy or hydrometallurgy encounter various challenges. This study aimed to explore the viability of solvometallurgical processes (solvoleaching) as potential alternatives for the extraction of these metals from their sulfides (CuS, Ni3S2, FeS, ZnS, PbS and MoS2). The solvometallurgical processes employed a range of solvoleaching systems, such as D2EHPA+MnO2+H2O, ammoniacal solvoleaching comprising of LIX 84-I+NH4OH+H2O2, HCl-equilibrated TBP (TBP-HCl) and EG (ethylene glycol)-based solvents containing each of HCl, FeCl3, ChCl and NH4Cl. The solvoleaching mechanism of the metal sulfides in each solvoleaching system was discussed. The results were corroborated with thermodynamic tools like Eh-pH diagrams, Gibbs free energy change, and solvation properties of the metal ions, as well as the hard and soft acid-base (HSAB) theory. Analyses of the resulting leach solutions, utilizing suitable analytical techniques such as UV–Vis spectroscopy and FTIR, provided additional support for the results. A comparison made between the solvoleaching and classical aqueous leaching, showing comparable results, indicated the viability of solvoleaching processes as alternatives for the sustainable extraction of these metals from their sulfides.
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来源期刊
Minerals Engineering
Minerals Engineering 工程技术-工程:化工
CiteScore
8.70
自引率
18.80%
发文量
519
审稿时长
81 days
期刊介绍: The purpose of the journal is to provide for the rapid publication of topical papers featuring the latest developments in the allied fields of mineral processing and extractive metallurgy. Its wide ranging coverage of research and practical (operating) topics includes physical separation methods, such as comminution, flotation concentration and dewatering, chemical methods such as bio-, hydro-, and electro-metallurgy, analytical techniques, process control, simulation and instrumentation, and mineralogical aspects of processing. Environmental issues, particularly those pertaining to sustainable development, will also be strongly covered.
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