{"title":"掺钒诱导 MoS2 同质结效应的原理及近红外光下抗菌过程的机理分析","authors":"","doi":"10.1016/j.seppur.2024.129814","DOIUrl":null,"url":null,"abstract":"<div><div>MoS<sub>2</sub> exhibits unique physical and chemical properties in its 1 T and 2H phases. Each phase has its inherent advantages and limitations. Although several biochemical properties of MoS<sub>2</sub> have been extensively reported, the specific impacts of these phases on photothermal and antibacterial performance, the feasibility of integrating the unique advantages of both phases and the underlying dominant bactericidal mechanisms are still largely unexplored. In this work, the electronic-structural relationships of 1 T- and 2H-MoS<sub>2</sub> were first simulated using density functional theory (DFT), which provided unique insights into how these phases affect performance. Based on these insights, a solid-state coupling interface and built-in electric field were designed between the two phases, and a 1 T/2H MoS<sub>2</sub> homojunction was synthesized using the hydrothermal method, achieving a higher carrier separation efficiency and exhibiting excellent photothermal and antibacterial properties. Subsequently, further attempts were made to adjust the electronic structure by doping vanadium atoms. This doping not only introduces additional electrons to facilitate electron transfer but also further enhances the antibacterial capability by creating surface defects that increase the number of active sites. Finally, the synergistic antibacterial mechanism of this system was thoroughly investigated through detailed experiments and DFT theoretical analysis. The design of the homojunction, the introduction of defects, and the incorporation of heteroatoms were discussed in this paper, which pave the way for the rational design strategy of advanced two-dimensional materials and can be extended to other polycrystalline materials.</div></div>","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Principle of vanadium doping-induced MoS2 homojunction effect and mechanism analysis of antibacterial process under near-infrared light\",\"authors\":\"\",\"doi\":\"10.1016/j.seppur.2024.129814\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>MoS<sub>2</sub> exhibits unique physical and chemical properties in its 1 T and 2H phases. Each phase has its inherent advantages and limitations. Although several biochemical properties of MoS<sub>2</sub> have been extensively reported, the specific impacts of these phases on photothermal and antibacterial performance, the feasibility of integrating the unique advantages of both phases and the underlying dominant bactericidal mechanisms are still largely unexplored. In this work, the electronic-structural relationships of 1 T- and 2H-MoS<sub>2</sub> were first simulated using density functional theory (DFT), which provided unique insights into how these phases affect performance. Based on these insights, a solid-state coupling interface and built-in electric field were designed between the two phases, and a 1 T/2H MoS<sub>2</sub> homojunction was synthesized using the hydrothermal method, achieving a higher carrier separation efficiency and exhibiting excellent photothermal and antibacterial properties. Subsequently, further attempts were made to adjust the electronic structure by doping vanadium atoms. This doping not only introduces additional electrons to facilitate electron transfer but also further enhances the antibacterial capability by creating surface defects that increase the number of active sites. Finally, the synergistic antibacterial mechanism of this system was thoroughly investigated through detailed experiments and DFT theoretical analysis. The design of the homojunction, the introduction of defects, and the incorporation of heteroatoms were discussed in this paper, which pave the way for the rational design strategy of advanced two-dimensional materials and can be extended to other polycrystalline materials.</div></div>\",\"PeriodicalId\":427,\"journal\":{\"name\":\"Separation and Purification Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2024-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Separation and Purification Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1383586624035536\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Separation and Purification Technology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1383586624035536","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
摘要
MoS2 的 1 T 相和 2H 相具有独特的物理和化学特性。每种相都有其固有的优势和局限性。尽管 MoS2 的一些生物化学特性已被广泛报道,但这些相态对光热和抗菌性能的具体影响、整合两种相态独特优势的可行性以及潜在的主导杀菌机制在很大程度上仍未得到探索。在这项工作中,首先使用密度泛函理论(DFT)模拟了 1 T 和 2H-MoS2 的电子结构关系,从而为了解这些相如何影响性能提供了独特的见解。在此基础上,设计了两相之间的固态耦合界面和内置电场,并利用水热法合成了 1 T/2H MoS2 同质结,实现了更高的载流子分离效率,并表现出优异的光热和抗菌性能。随后,研究人员进一步尝试通过掺杂钒原子来调整电子结构。这种掺杂不仅引入了额外的电子以促进电子转移,还通过产生表面缺陷增加了活性位点的数量,从而进一步增强了抗菌能力。最后,通过详细的实验和 DFT 理论分析,对该系统的协同抗菌机制进行了深入研究。本文讨论了同质结的设计、缺陷的引入和杂原子的结合,为先进二维材料的合理设计策略铺平了道路,并可推广到其他多晶材料。
Principle of vanadium doping-induced MoS2 homojunction effect and mechanism analysis of antibacterial process under near-infrared light
MoS2 exhibits unique physical and chemical properties in its 1 T and 2H phases. Each phase has its inherent advantages and limitations. Although several biochemical properties of MoS2 have been extensively reported, the specific impacts of these phases on photothermal and antibacterial performance, the feasibility of integrating the unique advantages of both phases and the underlying dominant bactericidal mechanisms are still largely unexplored. In this work, the electronic-structural relationships of 1 T- and 2H-MoS2 were first simulated using density functional theory (DFT), which provided unique insights into how these phases affect performance. Based on these insights, a solid-state coupling interface and built-in electric field were designed between the two phases, and a 1 T/2H MoS2 homojunction was synthesized using the hydrothermal method, achieving a higher carrier separation efficiency and exhibiting excellent photothermal and antibacterial properties. Subsequently, further attempts were made to adjust the electronic structure by doping vanadium atoms. This doping not only introduces additional electrons to facilitate electron transfer but also further enhances the antibacterial capability by creating surface defects that increase the number of active sites. Finally, the synergistic antibacterial mechanism of this system was thoroughly investigated through detailed experiments and DFT theoretical analysis. The design of the homojunction, the introduction of defects, and the incorporation of heteroatoms were discussed in this paper, which pave the way for the rational design strategy of advanced two-dimensional materials and can be extended to other polycrystalline materials.
期刊介绍:
Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.