Achieving high-thermal-conductivity brazed joint between carbon-based composites and Mo-Cu alloys by increasing the heat transfer area

Carbon-fiber-reinforced carbon matrix (C_f/C)-Mo30Cu brazed joints play an important role in the cooling systems of thermonuclear reactors. However, the limited contact area of heterogeneous interfaces severely limits the heat transfer efficiency. To overcome this drawback, we prepare three-dimensional porous interfaces by pre-oxidizing the C_f/C composite. Results show that circular gaps are formed between the carbon fibers and the pyrolyzed carbon after pre-oxidization at 600 °C in air. Fster braze penetration in the C_f/C composite is achieved, and the heat-transfer area across the interface is dramatically increased. The room-temperature thermal conductivity of the joints reaches a maximum value of 146 W·m⁻¹·K⁻¹ at a pre-oxidation time of 2 min; this value is 30 % higher than that obtained without treatment. The enhancement in thermal conductivity is mainly attributed to the increased contact area at the interface between the brazing seam and the C_f/C matrix, which provides more channels for heat transfer. This method of significantly improving the thermal conductivity is an important guide for the thermal management of thermonuclear reactors.