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Tailoring the microstructure and mechanical properties of laser metal deposited Hastelloy X superalloy via heat treatment and subsequent hot plastic deformation 通过热处理和随后的热塑性变形来定制激光金属沉积哈氏合金的显微组织和力学性能
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-30 DOI: 10.1016/j.jmatprotec.2024.118678
Zhubin He , Jiangkai Liang , Xianggang Ruan , Xuezhi Wang , Jian Ning , Quan Gao , Enyu Guo , Wei Du
The laser metal deposition technology, characterized by its inherent rapid cooling rate and high thermal gradient, poses significant challenges in fabricating large-scale, complex thin-walled Hastelloy X components that necessitate precise dimensional accuracy and structural integrity. To tackle this issue, a novel compound forming process is proposed, wherein a near-net-shaped preform is produced using laser metal deposition technology, followed by shape and properties regulation through the hot metal gas forming process. This investigation systematically explores the hot formability, pre-deformed microstructure and properties of Hastelloy X superalloy sheets fabricated through laser metal deposition, aiming to identify optimized process parameters and to validate the feasibility of this advanced forming process. Results indicate that: (1) The laser metal deposited Hastelloy X superalloy, subjected to solution and aging heat treatments, demonstrates remarkable microstructural integrity and exceptional hot formability, attributed to its pronounced overall crystalline texture and minimal dislocation density. (2) The optimal processing domain was established within a temperature range of 900 °C to 1000 °C and a strain rate of 0.001 s−1, as derived from hot processing maps based on dynamic material model. (3) Pre-deformation at 950 °C facilitates uniform and stable precipitation of nanoscale M23C6 carbides and the formation of a high-density dislocation network, significantly enhancing strength. Overall, through appropriate heat treatment and subsequent hot plastic deformation, the microstructure of Hastelloy X superalloy was optimized, yielding exceptional mechanical properties at both room and elevated temperatures. The feasibility of forming laser metal deposited preforms using the hot metal gas forming process was confirmed, laying a foundation for the future application of this innovative process. The methodologies and insights derived from this research are particularly relevant to the fabrication of large-sized, complex thin-walled components, especially within demanding aerospace applications and next-generation transportation systems.
激光金属沉积技术以其固有的快速冷却速度和高热梯度为特点,对制造大规模、复杂的薄壁哈氏合金X部件提出了重大挑战,这些部件需要精确的尺寸精度和结构完整性。为了解决这一问题,提出了一种新的复合成形工艺,其中采用激光金属沉积技术生产近网状预制体,然后通过热金属气体成形工艺调节形状和性能。本研究系统地研究了激光金属沉积制备哈氏合金X高温合金板材的热成形性能、预变形组织和性能,旨在确定优化的工艺参数,并验证该先进成形工艺的可行性。结果表明:(1)经过固溶热处理和时效热处理,激光金属沉积的哈氏合金具有明显的整体结晶组织和极小的位错密度,具有良好的显微组织完整性和热成形性。(2)根据基于动态材料模型的热加工图,在900°C ~ 1000°C、应变速率0.001 s−1范围内建立了最佳加工区域。(3) 950℃预变形有利于纳米级M23C6碳化物的均匀稳定析出和高密度位错网络的形成,强度显著提高。总的来说,通过适当的热处理和随后的热塑性变形,哈氏X高温合金的显微组织得到了优化,在室温和高温下都具有优异的机械性能。验证了采用热金属气体成形工艺成形激光金属沉积预制件的可行性,为该工艺的进一步应用奠定了基础。从这项研究中得出的方法和见解与大尺寸、复杂薄壁部件的制造特别相关,特别是在要求苛刻的航空航天应用和下一代运输系统中。
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引用次数: 0
Tailored microstructure and enhanced high temperature behavior of TiC/Inconel 718 composites through dual-gradient printing strategy in direct energy deposition 通过直接能量沉积双梯度印刷策略定制TiC/Inconel 718复合材料的微观结构和增强的高温行为
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-30 DOI: 10.1016/j.jmatprotec.2024.118679
Wenbo Liu , Bin Zou , Xinfeng Wang , Shouling Ding , Jikai Liu , Lei Li , Chuanzhen Huang , Peng Yao
The mismatch between the content of ceramics and laser power can lead to defects such as pores, microcracks, and grain coarsening, which resulted in the contradiction between tensile strength, ductility, and high-temperature behavior of TiC/superalloy composites. In this study, control methods for the microstructure evolution of TiC/Inconel 718 composites were investigated through dual-gradient printing strategy in direct energy deposition. Results indicated that this strategy, which involved a gradual increase in laser power and TiC addition amount in direct energy deposition processing, facilitated the transformation of Inconel 718–5 wt%TiC dual-gradient materials from columnar crystals to equiaxed crystals and the formation of carbides. This strategy effectively increased the number of heterogeneous nucleation points and solidification rate, while reducing temperature gradients, thereby forming a gradient-evolved microstructure. A significant amount of intragranular and intergranular carbides of the dual-gradient materials has enhanced stability of grains and grain boundaries at both room temperature and high temperature. Meanwhile, the internal fine equiaxed grains and carbides of Inconel 718–5 wt%TiC dual-gradient materials provided greater toughness. Inconel 718–5 wt%TiC dual-gradient materials exhibits a room temperature tensile strength of 859 MPa and an elongation of 18.2 %, along with a high temperature tensile strength of 746 MPa and a unit area oxidation weight gain of 0.5 mg/cm2. The dual-gradient printing strategy has addressed the contradiction between high tensile strength, low ductility, and high-temperature performance of TiC/Inconel 718 composites.
陶瓷含量与激光功率的不匹配会导致气孔、微裂纹和晶粒粗化等缺陷,从而导致TiC/高温合金复合材料的抗拉强度、塑性和高温性能之间的矛盾。在本研究中,研究了直接能量沉积双梯度印刷策略对TiC/Inconel 718复合材料微观结构演变的控制方法。结果表明,在直接能量沉积过程中,逐步提高激光功率和TiC添加量,有利于Inconel 718-5 wt%TiC双梯度材料由柱状晶向等轴晶转变,并形成碳化物。该策略有效地增加了非均相形核点的数量和凝固速度,同时减小了温度梯度,从而形成了梯度演化的微观组织。双梯度材料中大量的晶内和晶间碳化物增强了室温和高温下晶粒和晶界的稳定性。同时,Inconel 718-5 wt%TiC双梯度材料的内部细小等轴晶粒和碳化物具有较好的韧性。Inconel 718-5 wt%TiC双梯度材料室温抗拉强度为859 MPa,伸长率为18.2 %,高温抗拉强度为746 MPa,单位面积氧化增重0.5 mg/cm2。双梯度印刷策略解决了TiC/Inconel 718复合材料高抗拉强度、低延展性和高温性能之间的矛盾。
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引用次数: 0
Fabrication of micro holes with confined pitting corrosion by laser and electrochemical machining: Pitting corrosion formation mechanisms and protection method 用激光和电化学加工方法制备局限点蚀微孔:点蚀的形成机理和保护方法
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-28 DOI: 10.1016/j.jmatprotec.2024.118677
Jian Yang , Yufeng Wang , Yong Yang , Yunfeng Liu , Wenwu Zhang
Laser and electrochemical hybrid machining (LECM) combines the advantages of high efficiency of laser processing and high surface quality of electrochemical machining and has been employed to process deep micro holes with high surface quality, high precision, and efficiency. However, surface pitting corrosion occurs around the entrance of the micro holes drilled by LECM, which deteriorates their surface quality and mechanical properties. This study revealed the mechanism of surface pitting corrosion formation mechanisms during LECM by characterizing surface micromorphology, chemical composition, microstructures, and surface stress. The difference between surface pitting corrosion area during LECM and the stray current corrosion during electrochemical machining was studied. Micro solid metal particles and inner microcavities were observed in micro pits. The depth of the micro pits was greater than that obtained using electrochemical machining. It has been concluded that in LECM, the surface pitting corrosion occurred owing to the enhanced stray current corrosion and the accumulation of solidified melt particles and cavitation microbubbles in the micro pits. Coaxial gas-assisted LECM was also proposed to restrict the surface pitting corrosion area. Experiments and simulations were conducted to verify the feasibility of minimizing the corrosion area using coaxial gas. The surface pitting corrosion area has been decreased by 85.1 % at a coaxial gas pressure of 0.1 MPa compared with that without coaxial gas assistance. Finally, the radial cooling holes with a diameter of 1.2 mm and an aspect ratio of 125:1 in turbine blades with high surface quality were fabricated. This study provides a promising method to fabricate high-aspect-ratio micro-holes with high surface quality and high efficiency.
激光与电化学混合加工(LECM)结合了激光加工的高效率和电化学加工的高表面质量的优点,以高表面质量、高精度和高效率加工深微孔。然而,微孔的入口周围会发生表面点蚀,使微孔的表面质量和力学性能恶化。本研究通过表征表面微观形貌、化学成分、微观结构和表面应力,揭示了LECM过程中表面点蚀的形成机理。研究了电解加工过程中表面点蚀面积与电解加工过程中杂散电流腐蚀面积的差异。在微坑中观察到微小的固体金属颗粒和内部微腔。微凹坑的深度大于电化学加工的深度。结果表明,在LECM中,杂散电流腐蚀增强,微坑中熔体凝固颗粒和空化微泡的积累导致了表面点蚀的发生。此外,还提出了同轴气辅LECM,以限制表面点蚀面积。通过实验和仿真验证了利用同轴气体减小腐蚀面积的可行性。当共轴气体压力为0.1 MPa时,表面点蚀面积比无共轴气体辅助时减小了85.1% %。最后,在涡轮叶片上制备了直径为1.2 mm、展弦比为125:1的径向冷却孔,具有较高的表面质量。本研究提供了一种具有高表面质量和高效率的高纵横比微孔加工方法。
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引用次数: 0
Online pre-perception of forming state based on real-time measurement in spinning of thin-walled shell component 基于实时测量的薄壁壳件旋压成形状态在线预感知
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-26 DOI: 10.1016/j.jmatprotec.2024.118676
Xinggang Yan, Pengfei Gao, Mei Zhan, Xinshun Li, Han Zhang
Die-less spinning is an advance incremental forming process widely used for the manufacturing of thin-walled shell components. During the spinning, workpiece shape and forming state both change continuously, and the influence of process parameters on the forming results is also time-varying, which make it difficult to control the forming quality. To this end, this work develops a real-time measurement system and an online pre-perception method to provide technical support for dynamic control of the spinning process. Specifically, the real-time measurement system is constructed firstly by placing two laser profilers bilaterally at two sides of the workpiece. Based on the measuring data of two laser profilers, the profile data of workpiece cross-section is obtained by coordinate transformation, data denoising and correcting the error caused by inclined workpiece surface. Then, an algorithm is proposed to identify the critical geometric parameters (flange width, roller action radius, wall thickness and flange fluctuation degree) of workpiece shape from the profile data. In contrast to the measurement results by a three-coordinate measuring machine, the developed system presents a real-time measurement error less than 4 %. Moreover, an online pre-perception method of wall thickness and wrinkling defect is developed based on the real-time measured workpiece shape parameters. The online pre-perception of wall thickness and wrinkling defect presents high accuracy with the relative error less than 2.1 %. The above results indicate both the workpiece dimensions and spinning state can be well real-time measured and online pre-perceived, which can provide important foundation for the study of time-varying influence and dynamic control of the spinning process.
无模旋压是一种先进的增量成形工艺,广泛应用于薄壁壳件的制造。在旋压过程中,工件形状和成形状态都是连续变化的,工艺参数对成形结果的影响也是时变的,给成形质量的控制带来了困难。为此,本工作开发了实时测量系统和在线预感知方法,为纺纱过程的动态控制提供技术支持。具体而言,首先在工件两侧两侧放置两个激光轮廓仪,构建实时测量系统。以两台激光轮廓机的测量数据为基础,通过坐标变换、数据去噪和工件表面倾斜误差校正,得到工件截面轮廓数据。然后,提出了一种从型材数据中识别工件形状关键几何参数(凸缘宽度、滚轮作用半径、壁厚和凸缘起伏度)的算法。与三坐标测量机的测量结果相比,该系统的实时测量误差小于4 %。在此基础上,提出了一种基于实时测量工件形状参数的壁厚和起皱缺陷在线预感知方法。对壁厚和起皱缺陷的在线预感知精度较高,相对误差小于2.1 %。上述结果表明,工件尺寸和旋压状态都可以很好地实时测量和在线预感知,为研究旋压过程的时变影响和动态控制提供了重要的基础。
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引用次数: 0
An efficient high-quality cutting method for thick SiCf/SiC ceramic matrix composites using UV laser multiline layered scanning with focus increment optimization 利用紫外激光多线分层扫描和焦点增量优化,实现厚 SiCf/SiC 陶瓷基复合材料的高效优质切割方法
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-26 DOI: 10.1016/j.jmatprotec.2024.118674
Zhiwei Xu , Yuanyuan Jiang , Jinxuan Bai , Linmao Qian
Laser-layered scanning techniques have achieved considerable success in cutting and drilling applications. However, their effectiveness in processing SiCf/SiC ceramic matrix composites—critical materials for next-generation aerospace thermal components—remains less than optimal. This study addresses the challenge of enhancing the quality and efficiency of cutting thick samples by being the first to highlight the crucial influence of focus increment adjustments in the laser-layered scanning process. Specifically, it examines the relationship between the predetermined laser focus drop per layer and the actual ablation depth achieved. Systematic analysis explores the impact of focus increment adjustments on both the macroscopic structural alterations during cutting and the microstructural characteristics of the cut surfaces. The findings demonstrate that the UV nanosecond laser multi-line layered scanning technique is particularly effective for processing thick SiCf/SiC samples, achieving a surface area of 5 × 5 mm² (Sa 366.92 nm) in just 117.58 s. By optimising the focus increment, a high and stable material removal rate is maintained throughout the process, reducing surface oxidation, minimising the formation of a recast layer, and reducing fibre interface debonding. Additionally, the study reveals the mechanism behind the formation of surface taper and presents a method to achieve a taper-free surface by adjusting the laser incidence angle. These findings provide valuable insights for the rapid and high-quality machining of matrix composites, offering significant improvements over existing methods.
激光分层扫描技术在切割和钻孔应用中取得了巨大成功。然而,它们在加工 SiCf/SiC 陶瓷基复合材料(下一代航空航天热部件的关键材料)方面的效果仍未达到最佳。本研究首次强调了激光分层扫描过程中焦点增量调整的关键影响,从而解决了提高厚样品切割质量和效率的难题。具体来说,它研究了每层预定激光焦点下降与实际达到的烧蚀深度之间的关系。系统分析探讨了焦点增量调整对切割过程中宏观结构变化和切割表面微观结构特征的影响。研究结果表明,紫外纳秒激光多线分层扫描技术对处理厚的 SiCf/SiC 样品特别有效,只需 117.58 秒就能获得 5 × 5 mm² 的表面积(Sa 366.92 nm)。通过优化焦点增量,在整个加工过程中保持了较高且稳定的材料去除率,减少了表面氧化,最大限度地减少了重铸层的形成,并降低了纤维界面脱粘。此外,研究还揭示了表面锥度形成的机理,并提出了一种通过调整激光入射角实现无锥度表面的方法。这些发现为基体复合材料的快速和高质量加工提供了宝贵的见解,与现有方法相比有了显著的改进。
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引用次数: 0
Influence of Cu/Ni coating on microstructure and mechanical properties in steel/aluminum single-sided resistance spot welding joint 铜/镍涂层对钢/铝单面电阻点焊接头微观结构和机械性能的影响
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-25 DOI: 10.1016/j.jmatprotec.2024.118675
Gang Wang, Kang Zhou, Baokai Ren, Wenxiao Yu
Due to significant differences in physical and chemical properties between aluminum and steel, directly joining them using traditional resistance spot welding (RSW) process often cannot achieve satisfactory high-quality joints. In this work, some key factors influencing the quality of steel/aluminum welded joints were analyzed and a method based on fracture mechanism analysis was proposed aiming to improve the strength of steel/aluminum joints. The proposed method utilized a copper/nickel bimetallic coating on the steel surfaces, which was joined with aluminum alloy through single-sided RSW. This approach effectively addressed severe deformation of aluminum alloy and reduced stress cracks caused by residual stress in joints. Furthermore, the influence of coating on the microstructure and mechanical properties of steel/aluminum interface was further investigated. Experimental results showed the coating participated in interfacial metallurgical reactions, mainly forming intermetallic compounds (IMCs) such as Ni‍‍-Al, Fe-Cu, Cu-Al, and Fe-Ni, which mixed with Fe-Al compounds. Additionally, the coating refined the IMC grain size, resulting in smaller grains compared to Fe2Al5, the primary IMC in uncoated joints. Moreover, the coating reduced IMC layer thickness to within 2.0‍ μm at the weld center, and increased thinner IMC layer thickness by 0.4 μm at the weld periphery. This implied that the coating inhibited the mutual diffusion of Fe and Al atoms, preventing the formation of Fe-Al compounds and promoting a more uniform IMC layer thickness. Microhardness and tensile tests indicated that the coating reduced the hardness gradient of steel/aluminum interface, and increased IMC layer toughness and strength, improving the overall mechanical properties of the joints. The coated steel/aluminum joints with button fracture achieved a peak load of 6.7 kN and an average tensile-shear strength of 127.5 MPa, representing a 49.3 % increase in strength compared to uncoated steel/aluminum joints. This work will provide theoretical insights for steel/aluminum RSW and promote academic and practical engineering applications.
由于铝和钢在物理和化学性质上存在显著差异,使用传统的电阻点焊(RSW)工艺直接连接铝和钢往往无法获得令人满意的高质量焊点。本研究分析了影响钢/铝焊接接头质量的一些关键因素,并提出了一种基于断裂机理分析的方法,旨在提高钢/铝接头的强度。所提出的方法利用钢表面的铜/镍双金属涂层,通过单面 RSW 与铝合金连接。这种方法有效地解决了铝合金的严重变形问题,并减少了接头中残余应力引起的应力裂纹。此外,还进一步研究了涂层对钢/铝界面微观结构和机械性能的影响。实验结果表明,涂层参与了界面冶金反应,主要形成了金属间化合物(IMC),如 Ni‍‍-Al、Fe-Cu、Cu-Al 和 Fe-Ni,并与 Fe-Al 化合物混合。此外,涂层还细化了 IMC 晶粒大小,与未涂层接头中的主要 IMC Fe2Al5 相比,IMC 晶粒更小。此外,涂层还将焊缝中心的 IMC 层厚度减小到 2.0‍ μm 以内,并将焊缝外围较薄的 IMC 层厚度增加了 0.4 μm。这意味着涂层抑制了铁原子和铝原子的相互扩散,阻止了铁铝化合物的形成,并使 IMC 层厚度更加均匀。显微硬度和拉伸试验表明,涂层减少了钢/铝界面的硬度梯度,提高了 IMC 层的韧性和强度,改善了接头的整体机械性能。与未涂层的钢/铝接头相比,带钮扣断裂涂层的钢/铝接头达到了 6.7 kN 的峰值载荷和 127.5 MPa 的平均拉伸剪切强度,强度提高了 49.3%。这项工作将为钢/铝 RSW 提供理论依据,并促进学术和实际工程应用。
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引用次数: 0
Multimodal experimental and numerical evaluation of Residual Stress in AA6082-T6 Friction Stir Welding pipe girths AA6082-T6搅拌摩擦焊管径残余应力的多模态试验与数值计算
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-23 DOI: 10.1016/j.jmatprotec.2024.118665
Alessandro Tognan , Noel Sheshi , Emanuele Vaglio , Vladimir Luzin , Daniel Hattingh , Enrico Salvati
Although Residual Stress (RS) induced by Friction Stir Welding (FSW) has been widely investigated for planar weldments, the same attention has not been paid as far as the curved variant is concerned. To comprehensively address this gap, the present paper studies the RS in three AA6082-T6 FSW pipes (37.5 mm outer diameter × 3 mm thickness) manufactured with varying feed speeds, i.e. 50, 75, 100 mm/min. RS evaluations were cross-validated by two independent experimental methods, i.e. Neutron Diffraction and Contour Method. A novel multi-physics Finite Element (FE) model was implemented and calibrated using the previously obtained experimental outcomes to shed light on the key physical mechanism responsible for the arising of RS. The analysis unveiled M-like hoop RS patterns akin to flat FSW butt-welds but having lower magnitudes ranging from −20 MPa to 65 MPa, most likely due to the different thermal histories. The axial RS oscillates between -20 MPa and 20 MPa, whereas the radial component turned out to negligible. The FE model also demonstrated how feed speed, plunge force, and external clamping conditions alter RS magnitude while identifying 75 mm/min as the optimal speed that minimises the peak hoop RS to 40 MPa.
虽然搅拌摩擦焊在平面焊件中的残余应力问题已经得到了广泛的研究,但对于曲面焊件的残余应力问题却没有得到足够的重视。为了全面解决这一差距,本文研究了三种AA6082-T6 FSW管(外径37.5 mm ×厚度3mm)在不同进给速度(即50、75和100 mm/min)下制造的RS。RS评价采用中子衍射法和轮廓法两种独立的实验方法进行交叉验证。利用之前获得的实验结果,建立并校准了一种新的多物理场有限元(FE)模型,以阐明产生RS的关键物理机制。分析结果揭示了类似于FSW平对接焊缝的m形箍RS模式,但其强度较低,范围在- 20 MPa至65 MPa之间,很可能是由于不同的热历史。轴向RS在-20 MPa和20 MPa之间振荡,而径向分量则可以忽略不计。有限元模型还展示了进给速度、插入力和外部夹紧条件如何改变RS值,并确定75 mm/min为将箍箍峰值RS降至40 MPa的最佳速度。
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引用次数: 0
Single-crystal structure formation in laser directed energy deposited Inconel 718 through process parameter optimization and substrate orientation tuning 通过工艺参数优化和基底取向调整在激光定向能沉积 Inconel 718 中形成单晶结构
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-22 DOI: 10.1016/j.jmatprotec.2024.118673
Zuo Li , Xin Lin , Shang Sui , Xuan Zhao , Bo Yao , Chongliang Zhong , Andres Gasser , Hua Tan
A transverse grain boundary perpendicular to the applied loading direction is normally considered a main reason for the deterioration of the mechanical properties of nickel-based superalloys at high temperatures. Therefore, reducing or even eliminating these types of grain boundaries can effectively delay failure and improve high-temperature mechanical properties. In this study, the feasibility of process parameter optimization and substrate rotation was explored for fabricating single-crystal Inconel 718 specimens during laser directed energy deposition (LDED). The study determined that optimizing the process parameters was dependent on the ability to enlarge the [001] region at the bottom of the melt pool as much as possible. Simultaneously, ensuring that the remelting depth exceeded the stray grain region height at the top of the melt pool was necessary. Therefore, that the stray grains can be fully erased during the subsequent deposition process. Accordingly, an Inconel 718 single-walled specimen (height: 20 mm) with a full single-crystal structure was successfully fabricated using LDED for the first time. However, this approach remains insufficient for fabricating a block with a single-crystal structure, as SGs appear readily in the overlapping regions. Substrate rotation was further considered, where ensuring that one side of the melt pool was in the [001]-grain region was critical. Although the other side of the melt pool featured SGs, they were eliminated through the following overlapping process, as the SG region in the current melt pool corresponded to the [001]-grain region in the next melt pool. Through these two approaches, a small-format single-crystal block with dimensions of 27 × 8.3 × 1.3 mm (length × width × height) was successfully fabricated. Because the Inconel 718 superalloy is not specifically designed for single-crystal structure generation, a large-format block with a single-crystal structure still cannot be fabricated using these approaches. Nevertheless, the findings remain insightful because they demonstrate a wider range of variable microstructures achievable with additive manufacturing processes than with traditional forming processes such as casting or forging and may provide more opportunities for improving the mechanical properties. In addition, the preparation of a small-format single-crystal structure has significant applications in repairing damaged components such as aeroengine blades.
垂直于加载方向的横向晶界通常被认为是镍基超合金在高温下机械性能下降的主要原因。因此,减少甚至消除这类晶界可有效延缓失效并改善高温机械性能。本研究探讨了在激光定向能沉积(LDED)过程中制作单晶 Inconel 718 试样的工艺参数优化和基底旋转的可行性。研究发现,工艺参数的优化取决于尽可能扩大熔池底部 [001] 区域的能力。同时,必须确保重熔深度超过熔池顶部杂散晶粒区域的高度。因此,杂散晶粒可在随后的沉积过程中被完全清除。因此,利用 LDED 首次成功制造出了具有完整单晶结构的 Inconel 718 单壁试样(高度:20 毫米)。然而,这种方法仍不足以制造出具有单晶结构的块体,因为在重叠区域很容易出现 SG。我们进一步考虑了基底旋转的问题,其中确保熔池的一侧位于[001]晶粒区域至关重要。虽然熔池的另一侧出现了 SG,但由于当前熔池中的 SG 区域与下一个熔池中的 [001] 晶粒区域相对应,因此通过接下来的重叠过程消除了 SG。通过这两种方法,成功制造出了尺寸为 27 × 8.3 × 1.3 毫米(长 × 宽 × 高)的小规格单晶块。由于 Inconel 718 超耐热合金并非专为生成单晶结构而设计,因此使用这些方法仍无法制造出具有单晶结构的大规格晶块。尽管如此,这些研究结果仍然很有见地,因为与铸造或锻造等传统成型工艺相比,它们证明了增材制造工艺可实现的可变微观结构范围更广,并为改善机械性能提供了更多机会。此外,制备小尺寸单晶结构在修复航空发动机叶片等受损部件方面也有重要应用。
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引用次数: 0
Splashing effects and mechanism in water jet-guided laser processing of Cf/SiC composites 水射流引导激光加工 Cf/SiC 复合材料过程中的飞溅效应及其机理
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-19 DOI: 10.1016/j.jmatprotec.2024.118671
Binying Bao , Guangyi Zhang , Zhongan Chen , Yang Chao , Wenwu Zhang
Water jet-guided laser (WJGL) processing of ceramic matrix composites offers smooth cutting surfaces and minimizes defects such as delamination, burrs, and recast layers. However, the processing ability of WJGL is limited by the stability of the water jet. Splashing is a critical factor that affects water jet stability. This study investigates the splashing morphology and its impact mechanism during WJGL processing of continuous carbon fiber reinforced silicon carbide (Cf/SiC) composites. High-speed cameras were used to capture splashing morphologies and laser transmission states during drilling and grooving. The results indicate that the splashing morphology was significantly affected by the water jet speed and the micro-hole/groove depth, resulting in behaviors such as water accumulation, droplets falling, rebound droplets, splash impact, water film, and mist, which distorted or even broke the water jet. The laser escaped in the distorted water jet, leading to a reduction in material removal rate. The splashing at the water jet speed of 160 m/s resulted in a 61.1 % reduction in material removal rate during drilling compared to 40 m/s. In addition, a method of placing a porous water-absorbing material on the workpiece surface was proposed, which effectively improved the material removal rate. This paper presents a theoretical basis for comprehending and addressing splashing in WJGL processing.
水射流引导激光(WJGL)加工陶瓷基复合材料可提供光滑的切割表面,并最大限度地减少分层、毛刺和重铸层等缺陷。然而,WJGL 的加工能力受到水射流稳定性的限制。飞溅是影响水射流稳定性的一个关键因素。本研究调查了连续碳纤维增强碳化硅(Cf/SiC)复合材料在 WJGL 加工过程中的飞溅形态及其影响机制。在钻孔和开槽过程中,使用高速相机捕捉飞溅形态和激光传输状态。结果表明,水花形态受水射流速度和微孔/槽深度的影响很大,会出现积水、水滴下落、水滴反弹、水花冲击、水膜和水雾等行为,使水射流变形甚至断裂。激光在扭曲的水射流中逃逸,导致材料去除率降低。与 40 米/秒的水射流速度相比,160 米/秒的水射流速度下的飞溅导致钻孔过程中的材料去除率降低了 61.1%。此外,还提出了一种在工件表面放置多孔吸水材料的方法,有效提高了材料去除率。本文为理解和解决 WJGL 加工中的飞溅问题提供了理论依据。
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引用次数: 0
Achieving enhanced high-temperature strength in Ti-48Al-1Fe alloy sheets by direct hot pack-rolling of powder-sintered billets without cogging 通过直接热包轧粉末烧结坯料实现 Ti-48Al-1Fe 合金板材高温强度的增强而不产生钝化
IF 6.7 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2024-11-19 DOI: 10.1016/j.jmatprotec.2024.118669
Hanlin Wang , Ce Zhang , Xiangyang Liu , Hao Yu , Rui Liu , Jiazhen Zhang , Xin Lu
The TiAl alloy is a novel lightweight high-temperature structural material that exhibits exceptional performance. The brittleness and mechanical properties of the material can be enhanced by improving the microstructure via rolling. The Ti-48Al-1Fe alloy with high density was produced using powder compaction and pressure-less sintering. Subsequently, the TiAl alloy sheet was formed via hot pack rolling. This study examined the sheet formability of PM Ti-48Al-1Fe alloy sheets at various temperatures, as well as the microstructure and mechanical properties at varied levels of rolling deformations. The microstructure of the powder metallurgy (PM) TiAl alloy sheet has a unique duplex structure, consisting of α2/γ lamellar colonies and a composite structure. The rolling deformation process generates spherical recrystallized grains, which effectively reduce stress concentration. The enhanced composite structure is mostly localized at the interfaces between grains, creating a robust obstacle for the movement of dislocations at high temperatures. This results in the desired outcome of reinforcing the mechanical properties of the material at high temperatures through grain boundary strengthening. This study demonstrates that the ultimate tensile strength (UTS) of PM TiAl sheet tensile specimens in the rolling direction at room temperature is 443 MPa with 1 % elongation, whereas at 800 °C, the UTS rises to 548 MPa with 2.5 % elongation. This study proposes a novel process for the efficient production of Ti48Al1Fe sheets with good high-temperature mechanical properties. This technique entails the hot rolling of high-density sintered powder metallurgy billets, offering an innovative approach for the economical and swift production of TiAl alloy sheets during practical manufacturing process.
钛铝合金是一种新型轻质高温结构材料,具有优异的性能。通过轧制改善微观结构可提高材料的脆性和机械性能。利用粉末压制和无压烧结技术生产出了高密度的 Ti-48Al-1Fe 合金。随后,通过热包轧制形成了 TiAl 合金板材。本研究考察了粉末 Ti-48Al-1Fe 合金板材在不同温度下的成形性,以及在不同轧制变形水平下的微观结构和机械性能。粉末冶金(PM)TiAl 合金板材的微观结构具有独特的双相结构,由 α2/γ 层状菌落和复合结构组成。轧制变形过程会产生球形再结晶晶粒,从而有效减少应力集中。增强的复合结构主要集中在晶粒之间的界面上,为位错在高温下的移动提供了强有力的障碍。这就达到了通过晶界强化在高温下增强材料力学性能的预期效果。本研究表明, PM TiAl 板材拉伸试样在室温下沿轧制方向的极限拉伸强度(UTS)为 443 兆帕(伸长率为 1%),而在 800 °C 时,UTS 上升到 548 兆帕(伸长率为 2.5%)。本研究提出了一种高效生产具有良好高温机械性能的 Ti48Al1Fe 板材的新工艺。该技术需要对高密度烧结粉末冶金坯料进行热轧,为在实际生产过程中经济、快速地生产 TiAl 合金板材提供了一种创新方法。
{"title":"Achieving enhanced high-temperature strength in Ti-48Al-1Fe alloy sheets by direct hot pack-rolling of powder-sintered billets without cogging","authors":"Hanlin Wang ,&nbsp;Ce Zhang ,&nbsp;Xiangyang Liu ,&nbsp;Hao Yu ,&nbsp;Rui Liu ,&nbsp;Jiazhen Zhang ,&nbsp;Xin Lu","doi":"10.1016/j.jmatprotec.2024.118669","DOIUrl":"10.1016/j.jmatprotec.2024.118669","url":null,"abstract":"<div><div>The TiAl alloy is a novel lightweight high-temperature structural material that exhibits exceptional performance. The brittleness and mechanical properties of the material can be enhanced by improving the microstructure via rolling. The Ti-48Al-1Fe alloy with high density was produced using powder compaction and pressure-less sintering. Subsequently, the TiAl alloy sheet was formed via hot pack rolling. This study examined the sheet formability of PM Ti-48Al-1Fe alloy sheets at various temperatures, as well as the microstructure and mechanical properties at varied levels of rolling deformations. The microstructure of the powder metallurgy (PM) TiAl alloy sheet has a unique duplex structure, consisting of α<sub>2</sub>/γ lamellar colonies and a composite structure. The rolling deformation process generates spherical recrystallized grains, which effectively reduce stress concentration. The enhanced composite structure is mostly localized at the interfaces between grains, creating a robust obstacle for the movement of dislocations at high temperatures. This results in the desired outcome of reinforcing the mechanical properties of the material at high temperatures through grain boundary strengthening. This study demonstrates that the ultimate tensile strength (UTS) of PM TiAl sheet tensile specimens in the rolling direction at room temperature is 443 MPa with 1 % elongation, whereas at 800 °C, the UTS rises to 548 MPa with 2.5 % elongation. This study proposes a novel process for the efficient production of Ti48Al1Fe sheets with good high-temperature mechanical properties. This technique entails the hot rolling of high-density sintered powder metallurgy billets, offering an innovative approach for the economical and swift production of TiAl alloy sheets during practical manufacturing process.</div></div>","PeriodicalId":367,"journal":{"name":"Journal of Materials Processing Technology","volume":"335 ","pages":"Article 118669"},"PeriodicalIF":6.7,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142703457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Materials Processing Technology
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