{"title":"具有类似氧化酶活性的无金属碳点纳米酶作为光催化剂用于高效检测/还原六价铬和抗菌应用","authors":"","doi":"10.1016/j.seppur.2024.129852","DOIUrl":null,"url":null,"abstract":"<div><div>Wastewater containing Cr(VI) and bacteria indicated significant challenges and threats to public health and ecological environments. Hence, it is necessary to construct novel method for detecting and treatment such wastewater. Non-metal-doped carbon dots nanozyme (TA-CDs) were effectively synthesized by one-pot hydrothermal method utilizing tartaric acid (TA) and L-tryptophan (L-trp) as ingredients. TA-CDs revealed excellent water solubility, optical stability, and biocompatibility. Particularly noteworthy, TA-CDs (150 μg/mL) exhibited outstanding light-responsive oxidase-like activity, efficiently generating <span><math><mrow><msup><mrow><mtext>e</mtext></mrow><mtext>-</mtext></msup></mrow></math></span>, <span><math><mrow><msubsup><mtext>O</mtext><mrow><mtext>2</mtext></mrow><mrow><mo>∙</mo><mo>-</mo></mrow></msubsup></mrow></math></span> and <span><math><mrow><msubsup><mtext>CO</mtext><mrow><mtext>2</mtext></mrow><mrow><mo>∙</mo><mtext>-</mtext></mrow></msubsup></mrow></math></span>. Furthermore, TA-CDs illustrated an exceptional linear relationship with Cr(VI) in an extensive detection range and low detection limits (0.51 μM), as well as high selectivity and anti-interference properties. Simultaneously, TA-CDs also demonstrated significant photocatalytic activity, achieving approximately 70.26 % reduction in 40 mg/L Cr(VI) and realized excellent antimicrobial performance (inhibition rates of 97.18 % and 82.67 % against <em>E. coli</em> and <em>S. aureus</em>, respectively). In short, this research not only provided a multifunctional carbon-dots nanoenzyme for recognition, photoreduction of Cr(VI), and photodynamic antibacterial application, but also offered novel strategy and methodology for detection and treatment of water containing heavy metals and microorganisms.</div></div>","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metal-free carbon-dots nanozyme with oxidase-like activity as photocatalysts for highly efficient detection/reduction of Cr(VI) and antibacterial application\",\"authors\":\"\",\"doi\":\"10.1016/j.seppur.2024.129852\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Wastewater containing Cr(VI) and bacteria indicated significant challenges and threats to public health and ecological environments. Hence, it is necessary to construct novel method for detecting and treatment such wastewater. Non-metal-doped carbon dots nanozyme (TA-CDs) were effectively synthesized by one-pot hydrothermal method utilizing tartaric acid (TA) and L-tryptophan (L-trp) as ingredients. TA-CDs revealed excellent water solubility, optical stability, and biocompatibility. Particularly noteworthy, TA-CDs (150 μg/mL) exhibited outstanding light-responsive oxidase-like activity, efficiently generating <span><math><mrow><msup><mrow><mtext>e</mtext></mrow><mtext>-</mtext></msup></mrow></math></span>, <span><math><mrow><msubsup><mtext>O</mtext><mrow><mtext>2</mtext></mrow><mrow><mo>∙</mo><mo>-</mo></mrow></msubsup></mrow></math></span> and <span><math><mrow><msubsup><mtext>CO</mtext><mrow><mtext>2</mtext></mrow><mrow><mo>∙</mo><mtext>-</mtext></mrow></msubsup></mrow></math></span>. Furthermore, TA-CDs illustrated an exceptional linear relationship with Cr(VI) in an extensive detection range and low detection limits (0.51 μM), as well as high selectivity and anti-interference properties. Simultaneously, TA-CDs also demonstrated significant photocatalytic activity, achieving approximately 70.26 % reduction in 40 mg/L Cr(VI) and realized excellent antimicrobial performance (inhibition rates of 97.18 % and 82.67 % against <em>E. coli</em> and <em>S. aureus</em>, respectively). In short, this research not only provided a multifunctional carbon-dots nanoenzyme for recognition, photoreduction of Cr(VI), and photodynamic antibacterial application, but also offered novel strategy and methodology for detection and treatment of water containing heavy metals and microorganisms.</div></div>\",\"PeriodicalId\":427,\"journal\":{\"name\":\"Separation and Purification Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2024-09-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Separation and Purification Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1383586624035913\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Separation and Purification Technology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1383586624035913","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Metal-free carbon-dots nanozyme with oxidase-like activity as photocatalysts for highly efficient detection/reduction of Cr(VI) and antibacterial application
Wastewater containing Cr(VI) and bacteria indicated significant challenges and threats to public health and ecological environments. Hence, it is necessary to construct novel method for detecting and treatment such wastewater. Non-metal-doped carbon dots nanozyme (TA-CDs) were effectively synthesized by one-pot hydrothermal method utilizing tartaric acid (TA) and L-tryptophan (L-trp) as ingredients. TA-CDs revealed excellent water solubility, optical stability, and biocompatibility. Particularly noteworthy, TA-CDs (150 μg/mL) exhibited outstanding light-responsive oxidase-like activity, efficiently generating , and . Furthermore, TA-CDs illustrated an exceptional linear relationship with Cr(VI) in an extensive detection range and low detection limits (0.51 μM), as well as high selectivity and anti-interference properties. Simultaneously, TA-CDs also demonstrated significant photocatalytic activity, achieving approximately 70.26 % reduction in 40 mg/L Cr(VI) and realized excellent antimicrobial performance (inhibition rates of 97.18 % and 82.67 % against E. coli and S. aureus, respectively). In short, this research not only provided a multifunctional carbon-dots nanoenzyme for recognition, photoreduction of Cr(VI), and photodynamic antibacterial application, but also offered novel strategy and methodology for detection and treatment of water containing heavy metals and microorganisms.
期刊介绍:
Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.