{"title":"基于 CaO/ZSM-5 双催化剂的小麦秸秆催化热解与酸洗和预处理以提高生物油中的芳烃产量","authors":"Chenyang Sun, Zhen Zhou, Hong Tian, Shan Cheng, Hengyu He, Binbin Chen","doi":"10.1016/j.joei.2024.101836","DOIUrl":null,"url":null,"abstract":"<div><div>In this paper, the catalytic pyrolysis integrating combined pretreatment (acid washing and torrefaction) and dual catalysts was adopted to improve the quality of bio-oil and the selectivity of aromatic hydrocarbons. Combined pretreatment is a highly effective method to improve the quality of biomass feedstock. It was capable of the removal of alkali and alkaline earth metals from wheat straw, with a K removal rate of 97.79 %. Under the combined pretreatment, the aromatic hydrocarbon content in bio-oil increased to 68.8 % using the ZSM-5 catalyst alone. Compared with ZSM-5, CaO could remove part of the oxygenated functional groups and had a better acid removal effect, but the aromatic hydrocarbon yield was low to 7.95 %. After combined pretreatment using simulated aqueous phase bio-oil for acid washing, catalytic pyrolysis using CaO/ZSM-5 dual catalysts greatly enhanced the quality of the bio-oil. The oxygenated compounds content was reduced to 17.58 %, and the total hydrocarbon yield was increased to 82.42 %, especially the aromatic hydrocarbons yield was increased to 79.91 %, of which the monocyclic aromatic hydrocarbons were as high as 68.38 %, and the benzene, toluene, and xylene content reaching 49.39 %. Thus, integrating dual catalysts (CaO/ZSM-5) with combined pretreatment can effectively increase the aromatic yield for producing high-quality bio-oil.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"117 ","pages":"Article 101836"},"PeriodicalIF":5.6000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Catalytic pyrolysis of wheat straw based on dual catalyst CaO/ZSM-5 with acid washing and torrefaction pretreatment to enhance aromatic yield in bio-oils\",\"authors\":\"Chenyang Sun, Zhen Zhou, Hong Tian, Shan Cheng, Hengyu He, Binbin Chen\",\"doi\":\"10.1016/j.joei.2024.101836\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this paper, the catalytic pyrolysis integrating combined pretreatment (acid washing and torrefaction) and dual catalysts was adopted to improve the quality of bio-oil and the selectivity of aromatic hydrocarbons. Combined pretreatment is a highly effective method to improve the quality of biomass feedstock. It was capable of the removal of alkali and alkaline earth metals from wheat straw, with a K removal rate of 97.79 %. Under the combined pretreatment, the aromatic hydrocarbon content in bio-oil increased to 68.8 % using the ZSM-5 catalyst alone. Compared with ZSM-5, CaO could remove part of the oxygenated functional groups and had a better acid removal effect, but the aromatic hydrocarbon yield was low to 7.95 %. After combined pretreatment using simulated aqueous phase bio-oil for acid washing, catalytic pyrolysis using CaO/ZSM-5 dual catalysts greatly enhanced the quality of the bio-oil. The oxygenated compounds content was reduced to 17.58 %, and the total hydrocarbon yield was increased to 82.42 %, especially the aromatic hydrocarbons yield was increased to 79.91 %, of which the monocyclic aromatic hydrocarbons were as high as 68.38 %, and the benzene, toluene, and xylene content reaching 49.39 %. Thus, integrating dual catalysts (CaO/ZSM-5) with combined pretreatment can effectively increase the aromatic yield for producing high-quality bio-oil.</div></div>\",\"PeriodicalId\":17287,\"journal\":{\"name\":\"Journal of The Energy Institute\",\"volume\":\"117 \",\"pages\":\"Article 101836\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Energy Institute\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1743967124003143\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Energy Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1743967124003143","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Catalytic pyrolysis of wheat straw based on dual catalyst CaO/ZSM-5 with acid washing and torrefaction pretreatment to enhance aromatic yield in bio-oils
In this paper, the catalytic pyrolysis integrating combined pretreatment (acid washing and torrefaction) and dual catalysts was adopted to improve the quality of bio-oil and the selectivity of aromatic hydrocarbons. Combined pretreatment is a highly effective method to improve the quality of biomass feedstock. It was capable of the removal of alkali and alkaline earth metals from wheat straw, with a K removal rate of 97.79 %. Under the combined pretreatment, the aromatic hydrocarbon content in bio-oil increased to 68.8 % using the ZSM-5 catalyst alone. Compared with ZSM-5, CaO could remove part of the oxygenated functional groups and had a better acid removal effect, but the aromatic hydrocarbon yield was low to 7.95 %. After combined pretreatment using simulated aqueous phase bio-oil for acid washing, catalytic pyrolysis using CaO/ZSM-5 dual catalysts greatly enhanced the quality of the bio-oil. The oxygenated compounds content was reduced to 17.58 %, and the total hydrocarbon yield was increased to 82.42 %, especially the aromatic hydrocarbons yield was increased to 79.91 %, of which the monocyclic aromatic hydrocarbons were as high as 68.38 %, and the benzene, toluene, and xylene content reaching 49.39 %. Thus, integrating dual catalysts (CaO/ZSM-5) with combined pretreatment can effectively increase the aromatic yield for producing high-quality bio-oil.
期刊介绍:
The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include:
Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies
Emissions and environmental pollution control; safety and hazards;
Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS;
Petroleum engineering and fuel quality, including storage and transport
Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling
Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems
Energy storage
The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.