Photodegradation of 1,5-DHN to juglone as a biocompatible compound, using a metalloporphyrin-based mixed metal–metal organic framework: Synthesis, characterization, and photocatalytic behavior

In this study, our research was focused on the synthesis and characterizing of novel mixed metal–metal organic frameworks (MM-MOFs) incorporating porphyrin ligands. Furthermore, we investigated their performance in photodegrading 1,5-dihydroxynaphthalene (1,5-DHN) into 5-hydroxy-1,4-naphthalenedione (Juglone). Integrating metalloporphyrin-based ligands into bimetallic MOFs represents a pioneering advancement in this field. Photocatalytic reactions were conducted using various stoichiometric ratios of Co and Zn as metal nodes, along with meso-tetra(4-carboxyphenyl)porphyrin (TCPP-H₂) and Mn(III) meso-tetra(4-carboxyphenyl)porphyrin chloride (Mn-TCPP) as linkers. Results revealed that Co as a node led to the formation of nanorod metal–organic frameworks (MOF) structures, while Zn enhanced photocatalytic activity. Significantly, a photodegradation yield of 72% was achieved with a 1:3 molar ratio of Co to Zn in Zn_75%/Co₂₅ (TCPP-Mn), demonstrating a synergistic interplay between Co to Zn nodes and Mn-porphyrin linkers. Characterization was performed using structural and microscopic methods. Additionally, various parameters were optimized to elucidate the photocatalytic mechanism, revealing the promising potential of MM-MOFs for efficient photodegradation of 1,5-DHN and beyond. It is noteworthy that the integration of metalloporphyrin-based structures into MM-MOFs for photodegradation processes is relatively uncommon, underscoring the novelty and potential significance of incorporating porphyrin-based ligands in mixed metal MOFs for photodegradation applications.

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