感应加热强化甲醇蒸汽转化制氢的数值研究

Feng Wang , Delun Guan , Chuncen Wu , Xiuqin Zhang , Guoqiang Wang
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摘要

电磁感应加热技术具有非接触式热传导、热惯性小和温度管理方便等特点,本研究将其应用于提高催化甲醇蒸汽转化(MSR)反应过程。研究建立了一个二维反应器模型,该模型将电磁场耦合与 MSR 反应、流体动力学和传热学融为一体。在反应器中,通过电磁感应过程在磁性材料上瞬间产生热量,该过程由可再生能源发电产生。结果表明,内部-双排圆柱体(IN-DRC,圆柱体指感应加热元件的形状为圆柱形)的加热效率最高,为 38.3%,这受到 MSR 反应动力学的限制。内部-双排圆筒(IN-DRC)和内部-双排球(IN-DRB,球指感应加热元件的形状为球形)的甲醇转化率几乎相同,最高值接近 100%。此外,研究结果表明,在四种反应器设计中采用内部感应加热,而不是外部加热,可以有效缓解反应器内的温度梯度。因此,非接触式内部感应加热法具有大幅提高制氢工艺的潜力。
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Numerical study on induction heating enhanced methanol steam reforming for hydrogen production
Electromagnetic induction heating technology, characterized by its non-contact thermal heat transfer, diminished thermal inertia, and facile temperature management, is applied in this study to enhance catalytic methanol steam reforming (MSR) reaction process. A two-dimensional reactor model was developed integrating electromagnetic field coupling with MSR reactions, fluid dynamics and heat transfer. In the reactor, heat is induced instantaneously on the magnetic material through an electromagnetic induction process, which generated by renewable electricity. Results showed that the Internal - Double Row Cylinder (IN-DRC, cylinder means that the shape of induction heating element is cylindrical.) highest heating efficiency is 38.3%, which is limited by the kinetics of MSR reaction. Here, thermal efficiency reaches its maximum with the reaction channel outlet temperature reaching about 580 K. Internal - Double Row Cylinder (IN-DRC) and Internal - Double Row Ball (IN-DRB, ball means that the shape of induction heating element is spherical) methanol conversions are virtually identical, with a maximum value close to 100%. Furthermore, the findings that the adoption of internal induced heating, in contrast to external heating, across the four reactor designs can effectively mitigate temperature gradient within the reactors. This reduction in thermal disparity significantly amplifies methanol conversion within the reactor, thereby markedly enhancing its overall performance in hydrogen production.Therefore, non-contact internal induction heating method has the potential for substantially hydrogen production processes.
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