{"title":"用于传感 DMF 的多级分层自组装 ZnIn2S4/ZnO 柔性室温传感器","authors":"","doi":"10.1016/j.vacuum.2024.113709","DOIUrl":null,"url":null,"abstract":"<div><div>It's demanding to exploit flexible room temperature (FRT) sensors due to the hazardous effects of N, N-dimethylformamide (DMF) on human tissues. In this paper, ZnIn<sub>2</sub>S<sub>4</sub> (ZIS) is synthesised by solvothermal method, followed by the construction of ZIS/ZnO nanocomposites. The XRD and SEM confirm nanoflower-like ZIS is self-assembled from highly chemically active (110) nanosheets. The gas-sensing measurements indicate that the ZIS/ZnO FRT sensor exhibits excellent selectivity (100 ppm DMF, 78.35 %) and cycling stability, which is approximately a 39-fold improvement over ZnO sensor. In addition, the response decreases by only 5.43 % after 360 bends at 45°, and the response value of the sensor after 15 days is 72.02 %. The improved sensing characteristics can be attributed to the synergistic effect of increased specific surface area (61.09 g/cm<sup>2</sup>), linear ohmic contact and hetero-nanojunctions. The innovative material design provides a reference for improving the DMF detection efficiency of ZnO-based FRT sensor.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multi-stage hierarchical self-assembled ZnIn2S4/ZnO flexible room temperature sensor for DMF sensing\",\"authors\":\"\",\"doi\":\"10.1016/j.vacuum.2024.113709\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>It's demanding to exploit flexible room temperature (FRT) sensors due to the hazardous effects of N, N-dimethylformamide (DMF) on human tissues. In this paper, ZnIn<sub>2</sub>S<sub>4</sub> (ZIS) is synthesised by solvothermal method, followed by the construction of ZIS/ZnO nanocomposites. The XRD and SEM confirm nanoflower-like ZIS is self-assembled from highly chemically active (110) nanosheets. The gas-sensing measurements indicate that the ZIS/ZnO FRT sensor exhibits excellent selectivity (100 ppm DMF, 78.35 %) and cycling stability, which is approximately a 39-fold improvement over ZnO sensor. In addition, the response decreases by only 5.43 % after 360 bends at 45°, and the response value of the sensor after 15 days is 72.02 %. The improved sensing characteristics can be attributed to the synergistic effect of increased specific surface area (61.09 g/cm<sup>2</sup>), linear ohmic contact and hetero-nanojunctions. The innovative material design provides a reference for improving the DMF detection efficiency of ZnO-based FRT sensor.</div></div>\",\"PeriodicalId\":23559,\"journal\":{\"name\":\"Vacuum\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-10-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Vacuum\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0042207X24007553\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Vacuum","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0042207X24007553","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Multi-stage hierarchical self-assembled ZnIn2S4/ZnO flexible room temperature sensor for DMF sensing
It's demanding to exploit flexible room temperature (FRT) sensors due to the hazardous effects of N, N-dimethylformamide (DMF) on human tissues. In this paper, ZnIn2S4 (ZIS) is synthesised by solvothermal method, followed by the construction of ZIS/ZnO nanocomposites. The XRD and SEM confirm nanoflower-like ZIS is self-assembled from highly chemically active (110) nanosheets. The gas-sensing measurements indicate that the ZIS/ZnO FRT sensor exhibits excellent selectivity (100 ppm DMF, 78.35 %) and cycling stability, which is approximately a 39-fold improvement over ZnO sensor. In addition, the response decreases by only 5.43 % after 360 bends at 45°, and the response value of the sensor after 15 days is 72.02 %. The improved sensing characteristics can be attributed to the synergistic effect of increased specific surface area (61.09 g/cm2), linear ohmic contact and hetero-nanojunctions. The innovative material design provides a reference for improving the DMF detection efficiency of ZnO-based FRT sensor.
期刊介绍:
Vacuum is an international rapid publications journal with a focus on short communication. All papers are peer-reviewed, with the review process for short communication geared towards very fast turnaround times. The journal also published full research papers, thematic issues and selected papers from leading conferences.
A report in Vacuum should represent a major advance in an area that involves a controlled environment at pressures of one atmosphere or below.
The scope of the journal includes:
1. Vacuum; original developments in vacuum pumping and instrumentation, vacuum measurement, vacuum gas dynamics, gas-surface interactions, surface treatment for UHV applications and low outgassing, vacuum melting, sintering, and vacuum metrology. Technology and solutions for large-scale facilities (e.g., particle accelerators and fusion devices). New instrumentation ( e.g., detectors and electron microscopes).
2. Plasma science; advances in PVD, CVD, plasma-assisted CVD, ion sources, deposition processes and analysis.
3. Surface science; surface engineering, surface chemistry, surface analysis, crystal growth, ion-surface interactions and etching, nanometer-scale processing, surface modification.
4. Materials science; novel functional or structural materials. Metals, ceramics, and polymers. Experiments, simulations, and modelling for understanding structure-property relationships. Thin films and coatings. Nanostructures and ion implantation.