A Stable Layered Microporous MOF Assembled with Y-O Chains for Separation of MTO Products.

Benefiting from highly tunable pore environments, some metal-organic frameworks (MOFs) have recently shown promising prospects in the separation of methanol-to-olefin (MTO) products (mainly C₃H₆ and C₂H₄). However, the "trade-off" between gas storage capacity and selectivity always results in inefficient separation. In addition, poor stability of MOFs also limits practical separation applications. Herein, we have successfully assembled a layered Y-MOF (FJI-W9) with bent diisophthalate ligands (H₄L), Y-O chains, and 2-fluorobenzoic acids. As expected, FJI-W9 not only exhibits good chemical stability but also shows significant potential for C₃H₆/C₂H₄ separation. For FJI-W9, the C₃H₆ uptake at 298 K and 10 kPa is 63 cm³/g, and the IAST selectivity of FJI-W9 for C₃H₆/C₂H₄ (V/V = 50/50) is calculated to be 20.5. To the best of our knowledge, both C₃H₆ uptake and selectivity of FJI-W9 surpass most porous materials. GCMC simulation indicates that the special supramolecular binding sites in FJI-W9 have much stronger interactions with C₃H₆ than C₂H₄ molecules. More importantly, practical breakthrough experiments demonstrate that FJI-W9 can effectively separate C₃H₆/C₂H₄ (50/50) mixtures, thus obtaining high-purity C₂H₄ and C₃H₆, respectively.