Shilin Wang , Chenyu Zhang , Dapeng Chen , Yiming Qin , Lejun Xu , Yitong Li , Qinzheng Wang , Xuning Feng , Huaibin Wang
{"title":"大容量磷酸铁锂电池两相喷出物的爆炸特性","authors":"Shilin Wang , Chenyu Zhang , Dapeng Chen , Yiming Qin , Lejun Xu , Yitong Li , Qinzheng Wang , Xuning Feng , Huaibin Wang","doi":"10.1016/j.etran.2024.100377","DOIUrl":null,"url":null,"abstract":"<div><div>When a thermal runaway accident occurs in a lithium-ion battery energy storage station, the battery emits a large amount of flammable electrolyte vapor and thermal runaway gas, which may cause serious combustion and explosion accidents when they are ignited in a confined space. With the gradual development of large-scale energy storage batteries, the composition and explosive characteristics of thermal runaway products in large-scale lithium iron phosphate batteries for energy storage remain unclear. In this paper, the content and components of the two-phase eruption substances of 340Ah lithium iron phosphate battery were determined through experiments, and the explosion parameters of the two-phase battery eruptions were studied by using the improved and optimized 20L spherical explosion parameter test system, which reveals the explosion law and hazards of the two-phase battery eruptions. Studies have shown that in a two-phase system explosion, EMC can make the two-phase system more explosive and more powerful, and the thermal runaway gas expands its explosion concentration range. The coupling explosion of the two enhanced the sensitivity and explosive power of the two-phase ejecta. Increasing the concentration of any combustible in a two-phase system will cause the explosion intensity parameters of the system to increase. However, when the combustible concentration exceeds the optimal explosion concentration, the explosion intensity parameters will decrease or even no explosion will occur. Both explosion intensity parameters and sensitivity parameters are more sensitive to EMC concentration, and the higher the EMC concentration, the stronger its dominant role in the explosion of the two-phase system. This work can lay the foundation for revealing the disaster-causing mechanism of explosion accidents in lithium-ion battery energy storage power stations, guide the safe design of energy storage systems and the prevention and control of explosion accidents, and provide theoretical and data support for the investigation of explosion accidents in energy storage power stations.</div></div>","PeriodicalId":36355,"journal":{"name":"Etransportation","volume":null,"pages":null},"PeriodicalIF":15.0000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Explosion characteristics of two-phase ejecta from large-capacity lithium iron phosphate batteries\",\"authors\":\"Shilin Wang , Chenyu Zhang , Dapeng Chen , Yiming Qin , Lejun Xu , Yitong Li , Qinzheng Wang , Xuning Feng , Huaibin Wang\",\"doi\":\"10.1016/j.etran.2024.100377\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>When a thermal runaway accident occurs in a lithium-ion battery energy storage station, the battery emits a large amount of flammable electrolyte vapor and thermal runaway gas, which may cause serious combustion and explosion accidents when they are ignited in a confined space. With the gradual development of large-scale energy storage batteries, the composition and explosive characteristics of thermal runaway products in large-scale lithium iron phosphate batteries for energy storage remain unclear. In this paper, the content and components of the two-phase eruption substances of 340Ah lithium iron phosphate battery were determined through experiments, and the explosion parameters of the two-phase battery eruptions were studied by using the improved and optimized 20L spherical explosion parameter test system, which reveals the explosion law and hazards of the two-phase battery eruptions. Studies have shown that in a two-phase system explosion, EMC can make the two-phase system more explosive and more powerful, and the thermal runaway gas expands its explosion concentration range. The coupling explosion of the two enhanced the sensitivity and explosive power of the two-phase ejecta. Increasing the concentration of any combustible in a two-phase system will cause the explosion intensity parameters of the system to increase. However, when the combustible concentration exceeds the optimal explosion concentration, the explosion intensity parameters will decrease or even no explosion will occur. Both explosion intensity parameters and sensitivity parameters are more sensitive to EMC concentration, and the higher the EMC concentration, the stronger its dominant role in the explosion of the two-phase system. This work can lay the foundation for revealing the disaster-causing mechanism of explosion accidents in lithium-ion battery energy storage power stations, guide the safe design of energy storage systems and the prevention and control of explosion accidents, and provide theoretical and data support for the investigation of explosion accidents in energy storage power stations.</div></div>\",\"PeriodicalId\":36355,\"journal\":{\"name\":\"Etransportation\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":15.0000,\"publicationDate\":\"2024-10-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Etransportation\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2590116824000675\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Etransportation","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590116824000675","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Explosion characteristics of two-phase ejecta from large-capacity lithium iron phosphate batteries
When a thermal runaway accident occurs in a lithium-ion battery energy storage station, the battery emits a large amount of flammable electrolyte vapor and thermal runaway gas, which may cause serious combustion and explosion accidents when they are ignited in a confined space. With the gradual development of large-scale energy storage batteries, the composition and explosive characteristics of thermal runaway products in large-scale lithium iron phosphate batteries for energy storage remain unclear. In this paper, the content and components of the two-phase eruption substances of 340Ah lithium iron phosphate battery were determined through experiments, and the explosion parameters of the two-phase battery eruptions were studied by using the improved and optimized 20L spherical explosion parameter test system, which reveals the explosion law and hazards of the two-phase battery eruptions. Studies have shown that in a two-phase system explosion, EMC can make the two-phase system more explosive and more powerful, and the thermal runaway gas expands its explosion concentration range. The coupling explosion of the two enhanced the sensitivity and explosive power of the two-phase ejecta. Increasing the concentration of any combustible in a two-phase system will cause the explosion intensity parameters of the system to increase. However, when the combustible concentration exceeds the optimal explosion concentration, the explosion intensity parameters will decrease or even no explosion will occur. Both explosion intensity parameters and sensitivity parameters are more sensitive to EMC concentration, and the higher the EMC concentration, the stronger its dominant role in the explosion of the two-phase system. This work can lay the foundation for revealing the disaster-causing mechanism of explosion accidents in lithium-ion battery energy storage power stations, guide the safe design of energy storage systems and the prevention and control of explosion accidents, and provide theoretical and data support for the investigation of explosion accidents in energy storage power stations.
期刊介绍：
eTransportation is a scholarly journal that aims to advance knowledge in the field of electric transportation. It focuses on all modes of transportation that utilize electricity as their primary source of energy, including electric vehicles, trains, ships, and aircraft. The journal covers all stages of research, development, and testing of new technologies, systems, and devices related to electrical transportation.
The journal welcomes the use of simulation and analysis tools at the system, transport, or device level. Its primary emphasis is on the study of the electrical and electronic aspects of transportation systems. However, it also considers research on mechanical parts or subsystems of vehicles if there is a clear interaction with electrical or electronic equipment.
Please note that this journal excludes other aspects such as sociological, political, regulatory, or environmental factors from its scope.
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