{"title":"产生二次谐波的正交单晶双(3-氨基甲酰基吡啶-1-鎓)亚磷酸一水合物 (BCPP)","authors":"P. Vivek, R. Arunkumar","doi":"10.1007/s10854-024-13790-z","DOIUrl":null,"url":null,"abstract":"<div><p>The BCPP crystal was grown successfully. XRD confirmed the formation of BCPP and it belongs to noncentrosymmetric space group Pmn21 in the orthorhombic crystal system. UV measurements reveal that the BCPP crystal’s cut‐off wavelength is at 251 nm, with 54% transparency. The saturated intensity of BCPP is measured at 3.334 mW/cm<sup>2</sup>. The refractive index of the BCPP is 1.611. The BCPP exhibits birefringence values spanning from 0.2024 to 0.1012 in the visible spectrum. The LDT for BCPP is calculated to be 0.349 GW/cm. The BCPP crystal is mechanically stable up to 110 g. The SHG of BCPP is 3.7 times higher than that of the commonly used KDP. The deff value for BCPP single crystal is 0.797 pm/V.</p></div>","PeriodicalId":646,"journal":{"name":"Journal of Materials Science: Materials in Electronics","volume":"35 31","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Second harmonic generating orthorhombic single crystal bis(3-carbamoylpyridin-1-ium) phosphite monohydrate (BCPP)\",\"authors\":\"P. Vivek, R. Arunkumar\",\"doi\":\"10.1007/s10854-024-13790-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The BCPP crystal was grown successfully. XRD confirmed the formation of BCPP and it belongs to noncentrosymmetric space group Pmn21 in the orthorhombic crystal system. UV measurements reveal that the BCPP crystal’s cut‐off wavelength is at 251 nm, with 54% transparency. The saturated intensity of BCPP is measured at 3.334 mW/cm<sup>2</sup>. The refractive index of the BCPP is 1.611. The BCPP exhibits birefringence values spanning from 0.2024 to 0.1012 in the visible spectrum. The LDT for BCPP is calculated to be 0.349 GW/cm. The BCPP crystal is mechanically stable up to 110 g. The SHG of BCPP is 3.7 times higher than that of the commonly used KDP. The deff value for BCPP single crystal is 0.797 pm/V.</p></div>\",\"PeriodicalId\":646,\"journal\":{\"name\":\"Journal of Materials Science: Materials in Electronics\",\"volume\":\"35 31\",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Science: Materials in Electronics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10854-024-13790-z\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science: Materials in Electronics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10854-024-13790-z","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
Second harmonic generating orthorhombic single crystal bis(3-carbamoylpyridin-1-ium) phosphite monohydrate (BCPP)
The BCPP crystal was grown successfully. XRD confirmed the formation of BCPP and it belongs to noncentrosymmetric space group Pmn21 in the orthorhombic crystal system. UV measurements reveal that the BCPP crystal’s cut‐off wavelength is at 251 nm, with 54% transparency. The saturated intensity of BCPP is measured at 3.334 mW/cm2. The refractive index of the BCPP is 1.611. The BCPP exhibits birefringence values spanning from 0.2024 to 0.1012 in the visible spectrum. The LDT for BCPP is calculated to be 0.349 GW/cm. The BCPP crystal is mechanically stable up to 110 g. The SHG of BCPP is 3.7 times higher than that of the commonly used KDP. The deff value for BCPP single crystal is 0.797 pm/V.
期刊介绍：
The Journal of Materials Science: Materials in Electronics is an established refereed companion to the Journal of Materials Science. It publishes papers on materials and their applications in modern electronics, covering the ground between fundamental science, such as semiconductor physics, and work concerned specifically with applications. It explores the growth and preparation of new materials, as well as their processing, fabrication, bonding and encapsulation, together with the reliability, failure analysis, quality assurance and characterization related to the whole range of applications in electronics. The Journal presents papers in newly developing fields such as low dimensional structures and devices, optoelectronics including III-V compounds, glasses and linear/non-linear crystal materials and lasers, high Tc superconductors, conducting polymers, thick film materials and new contact technologies, as well as the established electronics device and circuit materials.
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