{"title":"碳质催化剂促进钠离子电池中 Na2S 的转化动力学","authors":"Xingjiang Wu , Xude Yu , Zhicheng Tian, Xiaowei Yang, Jianhong Xu","doi":"10.1016/j.ensm.2024.103899","DOIUrl":null,"url":null,"abstract":"<div><div>Conversion-type metal sulfide anode with high theoretical capacity has received increasing attention in Na-ion batteries (SIBs), but the irreversible conversion of Na<sub>2</sub>S intermediate in charging process usually engenders low rate capability and poor cycling stability. Herein, guided by DFT calculation, a new-type carbonaceous graphitic carbon nitride (g-CN) catalyst is first reported to boost conversion kinetics of Na<sub>2</sub>S intermediate to pristine MoS<sub>2</sub> in SIBs. Notably, the large chemisorbed energy, high selectivity and low catalytic energy barrier of g-CN catalyst can ensure its affluent charge transfers to Na<sub>2</sub>S intermediate, which chemically anchor and decompose Na<sub>2</sub>S intermediate for catalyzing its reversible conversion. Moreover, the microfluidic strategy is developed to enhance the mass diffusion of g-CN catalyst precursors into MoS<sub>2</sub> skeleton for facilitating their subsequently covalent bonding process. The covalent bonding of g-CN catalyst on 1T-MoS<sub>2</sub> (1T-MoS<sub>2</sub>/g-CN) superlattice with strong interfacial interaction via C-Mo bond can greatly promote Na<sup>+</sup>-storage kinetics of MoS<sub>2</sub> in discharging process and reversible conversion reaction of Na<sub>2</sub>S intermediate to pristine MoS<sub>2</sub> in following charging process, which is further evidenced by DFT calculation and in-situ characterizations. Consequently, the 1T-MoS<sub>2</sub>/g-CN superlattice reveals superb rate capacity and excellent cycling stability.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"74 ","pages":"Article 103899"},"PeriodicalIF":18.9000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Carbonaceous catalyst boosting conversion kinetics of Na2S in Na-ion batteries\",\"authors\":\"Xingjiang Wu , Xude Yu , Zhicheng Tian, Xiaowei Yang, Jianhong Xu\",\"doi\":\"10.1016/j.ensm.2024.103899\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Conversion-type metal sulfide anode with high theoretical capacity has received increasing attention in Na-ion batteries (SIBs), but the irreversible conversion of Na<sub>2</sub>S intermediate in charging process usually engenders low rate capability and poor cycling stability. Herein, guided by DFT calculation, a new-type carbonaceous graphitic carbon nitride (g-CN) catalyst is first reported to boost conversion kinetics of Na<sub>2</sub>S intermediate to pristine MoS<sub>2</sub> in SIBs. Notably, the large chemisorbed energy, high selectivity and low catalytic energy barrier of g-CN catalyst can ensure its affluent charge transfers to Na<sub>2</sub>S intermediate, which chemically anchor and decompose Na<sub>2</sub>S intermediate for catalyzing its reversible conversion. Moreover, the microfluidic strategy is developed to enhance the mass diffusion of g-CN catalyst precursors into MoS<sub>2</sub> skeleton for facilitating their subsequently covalent bonding process. The covalent bonding of g-CN catalyst on 1T-MoS<sub>2</sub> (1T-MoS<sub>2</sub>/g-CN) superlattice with strong interfacial interaction via C-Mo bond can greatly promote Na<sup>+</sup>-storage kinetics of MoS<sub>2</sub> in discharging process and reversible conversion reaction of Na<sub>2</sub>S intermediate to pristine MoS<sub>2</sub> in following charging process, which is further evidenced by DFT calculation and in-situ characterizations. Consequently, the 1T-MoS<sub>2</sub>/g-CN superlattice reveals superb rate capacity and excellent cycling stability.</div></div>\",\"PeriodicalId\":306,\"journal\":{\"name\":\"Energy Storage Materials\",\"volume\":\"74 \",\"pages\":\"Article 103899\"},\"PeriodicalIF\":18.9000,\"publicationDate\":\"2024-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy Storage Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2405829724007256\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Storage Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2405829724007256","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Carbonaceous catalyst boosting conversion kinetics of Na2S in Na-ion batteries
Conversion-type metal sulfide anode with high theoretical capacity has received increasing attention in Na-ion batteries (SIBs), but the irreversible conversion of Na2S intermediate in charging process usually engenders low rate capability and poor cycling stability. Herein, guided by DFT calculation, a new-type carbonaceous graphitic carbon nitride (g-CN) catalyst is first reported to boost conversion kinetics of Na2S intermediate to pristine MoS2 in SIBs. Notably, the large chemisorbed energy, high selectivity and low catalytic energy barrier of g-CN catalyst can ensure its affluent charge transfers to Na2S intermediate, which chemically anchor and decompose Na2S intermediate for catalyzing its reversible conversion. Moreover, the microfluidic strategy is developed to enhance the mass diffusion of g-CN catalyst precursors into MoS2 skeleton for facilitating their subsequently covalent bonding process. The covalent bonding of g-CN catalyst on 1T-MoS2 (1T-MoS2/g-CN) superlattice with strong interfacial interaction via C-Mo bond can greatly promote Na+-storage kinetics of MoS2 in discharging process and reversible conversion reaction of Na2S intermediate to pristine MoS2 in following charging process, which is further evidenced by DFT calculation and in-situ characterizations. Consequently, the 1T-MoS2/g-CN superlattice reveals superb rate capacity and excellent cycling stability.
期刊介绍:
Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field.
Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy.
Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.