新型介孔复合抑爆剂的铝粉尘抑爆性能与机理

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-10-28 DOI:10.1021/acsomega.4c0387110.1021/acsomega.4c03871
Xinyu Li, Haiyan Chen*, Yansong Zhang, Chunmiao Yuan, Hongzhao Wei, Wenxue Sun, Zhangjie Lu and Qingzhou Zhang, 
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引用次数: 0

摘要

本文利用20 L球形爆炸装置和哈特曼装置,对19和30 μm铝粉(500 g/m3)进行了不同浓度新型抑爆剂(MCM41@CS-APP)和CaCO3的抑爆实验,阐述了MCM41@CS-APP对铝粉的抑爆机理。实验结果表明,当抑爆剂浓度为 50 g/m3 时,混合粉尘爆炸产生的最大爆炸压力(Pmax)高于铝粉爆炸产生的最大爆炸压力(Pmax),且随着抑爆剂浓度的增加,混合粉尘的 Pmax 下降。当 MCM41@CS-APP 和 CaCO3 的浓度达到 400 g/m3 时,混合粉尘(Al = 19 μm)的 Pmax 分别为 0.133 和 0.364 MPa,分别降低了 81.3% 和 48.9%。混合粉尘(Al = 30 μm)的 Pmax 不显著。两种抑爆剂都抑制了铝粉的爆炸;Al/MCM41@CS-APP 的起爆持续时间更短;产品中的铝颗粒更少;铝粉的初始氧化温度更高。
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Aluminum Dust Explosion Suppression Performance and Mechanism of a New Mesoporous Composite Explosion Suppressant

In this paper, using a 20 L spherical explosive device and a Hartmann device, we carried out explosion suppression experiments on 19 and 30 μm aluminum powders (500 g/m3) with different concentrations of the new explosive suppressants (MCM41@CS-APP) and CaCO3 and elaborated on the suppression mechanism of the explosion of MCM41@CS-APP on aluminum powder. The experimental results show that when the concentration of the explosion suppressor is 50 g/m3, the maximum explosion pressure (Pmax) produced by the explosion of mixed dust is higher than that of the explosion of aluminum powder, and with the increase of the concentration of the deflagration suppressant, the Pmax of the mixed dust decreases. When the concentrations of MCM41@CS-APP and CaCO3 reached 400 g/m3, the Pmax of the mixed dust (Al = 19 μm) was 0.133 and 0.364 MPa, which decreased by 81.3% and 48.9%, respectively. The Pmax of the mixed dust (Al = 30 μm) was not significant. Both detonation inhibitors inhibited the explosion of aluminum powder; the detonation duration of Al/MCM41@CS-APP is shorter; there are fewer aluminum particles in the product; and the initial oxidation temperature of aluminum powder is higher.

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CiteScore
7.20
自引率
4.30%
发文量
567
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