Zhe Li, Zhaoyang Song, Linhua Liu, William W Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
{"title":"在 Zn2+/Li+-PC 有机电解质中扩大 V2O5 层间距，实现基于锌阳极的超稳定柔性电致变色显示器。","authors":"Zhe Li, Zhaoyang Song, Linhua Liu, William W Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li","doi":"10.1039/d4cc04974h","DOIUrl":null,"url":null,"abstract":"<p><p>To enhance the electrochemical stability and kinetics of V<sub>2</sub>O<sub>5</sub>, 3,4-ethylenedioxythiophene (EDOT) was <i>in situ</i> polymerized within V<sub>2</sub>O<sub>5</sub> interlayers, rendering PEDOT@V<sub>2</sub>O<sub>5</sub> with enlarged layer spacing, increased stability in organic electrolyte, and superior electrochemical kinetics (bleaching/coloration times 10.9/9.1 s) and cyclability (98.5% Δ<i>T</i> and 85.6% capacity retention after 1000 cycles) in a PEDOT@V<sub>2</sub>O<sub>5</sub>‖Zn electrochromic device.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Interlayer spacing expansion for V<sub>2</sub>O<sub>5</sub> towards ultra-stable zinc anode-based flexible electrochromic displays in Zn<sup>2+</sup>/Li<sup>+</sup>-PC organic electrolyte.\",\"authors\":\"Zhe Li, Zhaoyang Song, Linhua Liu, William W Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li\",\"doi\":\"10.1039/d4cc04974h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>To enhance the electrochemical stability and kinetics of V<sub>2</sub>O<sub>5</sub>, 3,4-ethylenedioxythiophene (EDOT) was <i>in situ</i> polymerized within V<sub>2</sub>O<sub>5</sub> interlayers, rendering PEDOT@V<sub>2</sub>O<sub>5</sub> with enlarged layer spacing, increased stability in organic electrolyte, and superior electrochemical kinetics (bleaching/coloration times 10.9/9.1 s) and cyclability (98.5% Δ<i>T</i> and 85.6% capacity retention after 1000 cycles) in a PEDOT@V<sub>2</sub>O<sub>5</sub>‖Zn electrochromic device.</p>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4cc04974h\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc04974h","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte.
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, and superior electrochemical kinetics (bleaching/coloration times 10.9/9.1 s) and cyclability (98.5% ΔT and 85.6% capacity retention after 1000 cycles) in a PEDOT@V2O5‖Zn electrochromic device.
期刊介绍：
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
