Mihály Purgel , A. Jalila Simaan , Yongxing Wang , Marius Réglier , Michel Giorgi , József Kaizer
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Reinvestigation of the mechanism of the enamine-mediated dioxygen activation
The reaction of cyclohexylidene-2-carbamylcyclohex-1-enylamines with molecular oxygen does not undergo a [4+2] cycloaddition reactions but leads mainly to a dimer via single electron transfer (SET) from the enamine to 3O2, proton transfer (PT) and consecutive radical C–C coupling, an addition to the formation of hydroperoxide byproduct.
期刊介绍：
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
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– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
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Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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