{"title":"MoNbVTa0.5Alx 高熵难熔合金的微观结构和力学性能","authors":"Wei Guo , Mengyuan Zhu , Sheng Yu , Weijie Zheng , Mi Zhao , Shulin Lü , Shusen Wu","doi":"10.1016/j.ijrmhm.2024.106960","DOIUrl":null,"url":null,"abstract":"<div><div>The specific strength of refractory high entropy alloys (RHEAs) is usually impaired due to the high density of constituent elements. In order to develop a low-density RHEA, the microstructure and mechanical property of MoNbVTa<sub>0.5</sub>-based RHEAs with various Al additions have been investigated in this study. All samples exhibited a monolithic BCC solid solution structure. The addition of Al resulted in improved yield strength but a degraded plasticity at ambient temperature. In contrast, the yield strength consistently decreased with increasing Al content at elevated temperatures, and the softening occurred at ∼1000 °C. MoNbVTa<sub>0.5</sub>Al<sub>0.3</sub> exhibited high specific strengths of 119.2 MPa cm<sup>3</sup>/g, 108.6 MPa cm<sup>3</sup>/g and 97.3 MPa cm<sup>3</sup>/g at 600 °C, 800 °C, and 1000 °C, respectively.</div></div>","PeriodicalId":14216,"journal":{"name":"International Journal of Refractory Metals & Hard Materials","volume":"126 ","pages":"Article 106960"},"PeriodicalIF":4.2000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructure and mechanical properties of MoNbVTa0.5Alx refractory high entropy alloys\",\"authors\":\"Wei Guo , Mengyuan Zhu , Sheng Yu , Weijie Zheng , Mi Zhao , Shulin Lü , Shusen Wu\",\"doi\":\"10.1016/j.ijrmhm.2024.106960\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The specific strength of refractory high entropy alloys (RHEAs) is usually impaired due to the high density of constituent elements. In order to develop a low-density RHEA, the microstructure and mechanical property of MoNbVTa<sub>0.5</sub>-based RHEAs with various Al additions have been investigated in this study. All samples exhibited a monolithic BCC solid solution structure. The addition of Al resulted in improved yield strength but a degraded plasticity at ambient temperature. In contrast, the yield strength consistently decreased with increasing Al content at elevated temperatures, and the softening occurred at ∼1000 °C. MoNbVTa<sub>0.5</sub>Al<sub>0.3</sub> exhibited high specific strengths of 119.2 MPa cm<sup>3</sup>/g, 108.6 MPa cm<sup>3</sup>/g and 97.3 MPa cm<sup>3</sup>/g at 600 °C, 800 °C, and 1000 °C, respectively.</div></div>\",\"PeriodicalId\":14216,\"journal\":{\"name\":\"International Journal of Refractory Metals & Hard Materials\",\"volume\":\"126 \",\"pages\":\"Article 106960\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Refractory Metals & Hard Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0263436824004086\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Refractory Metals & Hard Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263436824004086","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Microstructure and mechanical properties of MoNbVTa0.5Alx refractory high entropy alloys
The specific strength of refractory high entropy alloys (RHEAs) is usually impaired due to the high density of constituent elements. In order to develop a low-density RHEA, the microstructure and mechanical property of MoNbVTa0.5-based RHEAs with various Al additions have been investigated in this study. All samples exhibited a monolithic BCC solid solution structure. The addition of Al resulted in improved yield strength but a degraded plasticity at ambient temperature. In contrast, the yield strength consistently decreased with increasing Al content at elevated temperatures, and the softening occurred at ∼1000 °C. MoNbVTa0.5Al0.3 exhibited high specific strengths of 119.2 MPa cm3/g, 108.6 MPa cm3/g and 97.3 MPa cm3/g at 600 °C, 800 °C, and 1000 °C, respectively.
期刊介绍:
The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.