铜插层 ZrSe2 时电子化学势的变化

IF 2.7 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Letters Pub Date : 2024-11-06 DOI:10.1016/j.matlet.2024.137673

A.S. Shkvarin, E.A. Suslov, M.S. Postnikov, A.N. Titov

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引用次数: 0

摘要

根据对 CuxZrSe2 中 Zr3d 和 Se3d 核级的结合能以及电化学实验中的电动势的分析，确定了铜在 CuxZrSe2 中浓度为 x = 0.25 时的有效价。

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The shift in chemical potential of electrons upon intercalation of ZrSe2 by copper

The effective valence of copper in the region of its concentration up to x = 0.25 in Cu_xZrSe₂ has been determined based on an analysis of binding energies of the Zr3d and Se3d core levels and the electromotive forces from an electrochemical experiment for Cu_xZrSe₂, as a function of Cu concentration x. It has been shown that the domination of covalent bonding between copper and the ZrSe₂ host lattice within this concentration range results in a notable reduction in the effective valence of copper in comparison to its nominal value.

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来源期刊

Materials Letters 工程技术-材料科学：综合

CiteScore

5.60

自引率

3.30%

发文量

1948

审稿时长

50 days

期刊介绍： Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials. Contributions include, but are not limited to, a variety of topics such as: • Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors • Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart • Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction • Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots. • Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing. • Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic • Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive