Multi-scale fatigue damage analysis in filament-wound carbon fiber reinforced epoxy composites for hydrogen storage tanks

This article presents the findings of a multi-scale experimental study on carbon fiber-reinforced epoxy composites (CFRP) used in lightweight hydrogen storage pressure vessels produced via filament winding. The research employs a combination of tension-tension load-controlled fatigue tests and high-resolution physical-chemical characterization and porosity quantification to assess the impact of porosity on mechanical performance. The findings demonstrate that porosity has a detrimental impact on mechanical properties, acting as nucleation sites for damage mechanisms such as crack initiation, fiber-matrix separation and fiber breakage. At the mesoscopic level, microdefects coalesce into transverse cracks and delamination, resulting in complex failure modes under cyclic loading. The results of the tensile tests demonstrated that the orientation of the fibers has a significant impact on the mechanical behavior of the material. The ±15° configuration demonstrated superior tensile strength and modulus, while the ±30° and multilayer configurations exhibited higher ductility. The results of the fatigue testing confirmed that fiber orientation has a significant impact on fatigue life, with the ±15° configuration proving to be the most resistant. Microscopic analysis indicated that pores act as damage initiation points, accelerating failure through matrix cracking, fiber-matrix debonding, and delamination. This study highlights the need for improved porosity control during manufacturing to enhance the durability of hydrogen storage systems. Additionally, it provides valuable insights for optimizing fiber orientation to improve fatigue performance in practical applications.