热处理聚四氟乙烯/聚二甲基硅氧烷/纳米二氧化硅沉积层以制备具有防腐蚀、防结垢和防污性能的超疏水涂层

IF 1.9 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY ChemistrySelect Pub Date : 2024-11-18 DOI:10.1002/slct.202404251
Zichao Yin, Zhenhua Sun, Junyi Li, Haigang Zhou, Jingjing Qi, Weidong Wang
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引用次数: 0

摘要

对聚四氟乙烯基超疏水涂层的研究日益增多,所制备的涂层具有优异的防腐蚀、防结垢、防污和防结冰性能。为了进一步增强聚四氟乙烯涂层的疏水性,研究人员通过沉积涂层和退火处理,制备了一种由纳米二氧化硅和聚二甲基硅氧烷(PDMS)组成的聚四氟乙烯基涂层。涂层的水接触角和滑动角分别达到了 160.65°和 3.02°,证明其具有超疏水特性。由于其优异的表面特性,涂层具有耐牛奶、咖啡和泥水的性能,并且很容易被水流清洗。此外,涂层上的水滴凝固时间较长,冰滴很容易从涂层上清除。丰富的非极性基团和在水中形成的气垫使制备的涂层具有优异的防结垢和防腐蚀性能。与无涂层的钢板(78.2 Ω-cm2)相比,有涂层钢板的电化学阻抗(9000 Ω-cm2以上)提高了两个数量级,涂层对BaSO4和SrSO4的抗垢率均在80%以上。该涂层有望在许多应用领域成为具有竞争力的候选材料。
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Heat Treatment of PTFE/PDMS/Nano-silica Deposited Layer for Preparation of Superhydrophobic Coating with Anti-corrosion, Anti-scaling, and Anti-fouling Properties

PTFE-based superhydrophobic coatings have received increasing research and the fabricated coatings exhibited excellent anti-corrosion, anti-scaling, anti-fouling, and anti-icing properties. In order to further enhance the hydrophobicity of PTFE coating, a PTFE-based coating consisted of nano-silica and polydimethylsiloxane (PDMS) was fabricated by deposition coating and annealing treatment. The water contact angle and sliding angle of the coating achieved 160.65° and 3.02°, respectively, demonstrating it possessed superhydrophobic property. Due to its excellent surface feature, the coating exhibited resistance to milk, coffee, and mud water, and could be easily cleaned by water flow. Besides, the water droplet on the coating had a longer freezing time and the ice droplet could be easily removed from the coating. Ascribed to the abundant nonpolar groups and the air cushion formed under water, the prepared coating had outstanding anti-scaling and anti-corrosion properties. The electrochemical impedance of the steel plate with the coating (above 9000 Ω·cm2) increased by two orders of magnitude compared with the non-coating one (78.2 Ω·cm2), and the anti-scaling rates of the coating towards BaSO4 and SrSO4 were all above 80%. It is promising that the coating will be a competitive candidate in many application fields.

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来源期刊
ChemistrySelect
ChemistrySelect Chemistry-General Chemistry
CiteScore
3.30
自引率
4.80%
发文量
1809
审稿时长
1.6 months
期刊介绍: ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
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